100809-50-5Relevant academic research and scientific papers
Selective P-C bond cleavage of tertiary phosphine boranes by sodium
Zhang, Jian-Qiu,Ye, Jing-Jing,Han, Li-Biao
, p. 961 - 964 (2021)
Herein reported is the facial modification of tertiary phosphine boranes R3PBH3 by selective cleaving the P-Ph bond by sodium in which the phosphide borohydride R2PNa(BH3) is quantitatively generated and could be easily quenched by electrophiles to furnish a series of new phosphine boranes in high yields.
