100812-08-6

Basic information

• Product Name: 2,2-Dimethyl-propionic acid 2-[(E)-tert-butylimino]-1-methyl-1-phenyl-ethyl ester
• CAS NO: 100812-08-6
• Molecular Weight: 289.418
• Mol File: 100812-08-6.mol

Chemical Properties

• CAS DataBase Reference: 2,2-Dimethyl-propionic acid 2-[(E)-tert-butylimino]-1-methyl-1-phenyl-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Dimethyl-propionic acid 2-[(E)-tert-butylimino]-1-methyl-1-phenyl-ethyl ester(100812-08-6)
• EPA Substance Registry System: 2,2-Dimethyl-propionic acid 2-[(E)-tert-butylimino]-1-methyl-1-phenyl-ethyl ester(100812-08-6)

Safety Data

• Hazardous Substances Data: 100812-08-6(Hazardous Substances Data)

Upstream product

• 34713-70-7 2-Phenylpropanal 
• 3282-30-2 pivaloyl chloride 
• 85664-58-0 (Z)-2-methyl-N-(2-phenylpropylidene)propan-2-amine N-oxide 

Downstream Products

• 85664-70-6 2-<(2,2-dimethylpropanoyl)oxy>-2-phenylpropanal 
• 55915-75-8 α-<((1,1-dimethylethyl)amino)methyl>-α-methylbenzenemethanol 

Relevant articles and documents

Preparation of Vicinal N-Alkylamino Alcohols via Acylation-Rearrangement of Nitrones Followed by Hydride Reduction

Acylation-rearrangement of N-tert-butyl and N-cyclohexyl nitrones of cyclohexanecarboxaldehyde (1), n-butyraldehyde, isobutyraldehyde, 3-cyclohexenecarboxaldehyde, and α-methylpropionaldehyde gave α-pivaloyloxy imines, which underwent reduction with lithi

α-Oxygenation of Aldehydes and Cyclic Ketones by Acylation-Rearrangement of Nitrones

The reaction of N-tert-butylnitrones (1a-e) of aldehydes and N-methylnitrones (2 and 3) of cyclic ketones with acid chlorides in the presence of triethylamine afforded α-acyloxy imines by rearrangement of N-vinyl-O-acylhydroxylamine intermediates.Hydrolysis of the α-acyloxy imines gave α-acyloxy aldehydes and ketones.The acylation-rearrangement reaction offers a new method for α-oxygenation of carbonyl compounds.