100818-58-4Relevant academic research and scientific papers
Rhodium Complex-Catalyzed Reaction of Isonitriles with Carbonyl Compounds: Catalytic Synthesis of Pyrroles
Takaya, Hikaru,Kojima, Sachiko,Murahashi, Shun-Ichi
, p. 421 - 424 (2001)
(Matrix Presented) Low-valent rhodium complexes are efficient catalysts for the activation of α-C-H bond of isonitriles. Addition of isonitriles to carbonyl compounds proceeds under mild and neutral conditions to give the corresponding α,β-unsaturated for
FLUOROPYRROLES AND TETRAFLUOROPORPHYRINS
Onda, Hiroyuki,Toi, Hiroo,Aoyama, Yasuhiro,Ogoshi, Hisanobu
, p. 4221 - 4224 (2007/10/02)
Photolysis of pyrrole-β-diazonium tetrafluoroborates gave β-fluoropyrroles.These were further converted to 1,3,5,7-tetrafluoroporphyrins, the first example of ring-fluorinated porphyrin derivatives.
