1008750-48-8Relevant academic research and scientific papers
Reactivity of a coordinatively unsaturated Cp*Ru(κ2- P,O) complex
Rankin, Matthew A.,Hesp, Kevin D.,Schatte, Gabriele,McDonald, Robert,Stradiotto, Mark
, p. 250 - 252 (2008)
Whereas a new coordinatively unsaturated Cp*Ru(κ2-P, O) complex (1a) forms adducts with two-electron donors (including σ-H 2 and μ-N2 ligands), double Si-H bond activation is observed upon treatment with Ph2SiH2 or PhSiH3, leading to the clean formation of products corresponding to the net insertion of a Ph2Si: or Ph(H)Si: fragment into the Ru-O bond of 1a. The Royal Society of Chemistry.
Exploring the reactivity of a coordinatively unsaturated Cp*Ru(κ2-P,O) complex with small molecule substrates: Application in E-H bond activation (E = H, B, and Si)
Rankin, Matthew A.,Hesp, Kevin D.,Schatte, Gabriele,McDonald, Robert,Stradiotto, Mark
, p. 4756 - 4765 (2009)
Treatment of [Cp*RuCl]4 with 1-diisopropylphosphino-2- indanone (1) afforded Cp*Ru(Cl)(κ2-P,O-1) (2) in 96% isolated yield. Dehydrohalogenation of 2 under an atmosphere of N2 provided the dinuclear complex 4 (78% isolated
