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100900-16-1

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100900-16-1 Usage

Uses

1,4-Chrysenequinone, is a polycyclic aromatic quinone, that can act as an activator of aryl hydrocarbon receptor (AhR).

Check Digit Verification of cas no

The CAS Registry Mumber 100900-16-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,0,9,0 and 0 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 100900-16:
(8*1)+(7*0)+(6*0)+(5*9)+(4*0)+(3*0)+(2*1)+(1*6)=61
61 % 10 = 1
So 100900-16-1 is a valid CAS Registry Number.
InChI:InChI=1/C18H10O2/c19-16-9-10-17(20)18-14-6-5-11-3-1-2-4-12(11)13(14)7-8-15(16)18/h1-10H

100900-16-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,4-Chrysenequinone

1.2 Other means of identification

Product number -
Other names chrysene-1,4-dione

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:100900-16-1 SDS

100900-16-1Synthetic route

1-vinylnaphthalene
826-74-4

1-vinylnaphthalene

(+/-)-2-(p-tolylsulfinyl)-1,4-benzoquinone

(+/-)-2-(p-tolylsulfinyl)-1,4-benzoquinone

benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

Conditions
ConditionsYield
In dichloromethane at 20℃; under 9000720 Torr; for 18h;80%
1-hydroxy-chrysene
63019-38-5

1-hydroxy-chrysene

benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

Conditions
ConditionsYield
With potassium nitrososulfonate
1-vinylnaphthalene
826-74-4

1-vinylnaphthalene

p-benzoquinone
106-51-4

p-benzoquinone

benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

Conditions
ConditionsYield
With acetic acid at 100℃;
1-vinylnaphthalene
826-74-4

1-vinylnaphthalene

benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

phenanthro[1,2-b]chrysene-7,16-dione
122446-36-0

phenanthro[1,2-b]chrysene-7,16-dione

benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

chrysene
218-01-9

chrysene

Conditions
ConditionsYield
With tetrahydrofuran; lithium aluminium tetrahydride
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

1,4-chrysenediol
101875-22-3

1,4-chrysenediol

Conditions
ConditionsYield
With 1,4-dioxane; sodium dithionite; tin(ll) chloride weitere Reagenzien: wss. HCl, Essigsaeure;
With sodium tetrahydroborate In acetone
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

acetic anhydride
108-24-7

acetic anhydride

1,4-diacetoxy-chrysene
110877-25-3

1,4-diacetoxy-chrysene

Conditions
ConditionsYield
With pyridine; zinc
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

acetic anhydride
108-24-7

acetic anhydride

1,2,4-triacetoxy-chrysene
113113-87-4

1,2,4-triacetoxy-chrysene

Conditions
ConditionsYield
With sulfuric acid
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

A

phenanthrene-1,2-dicarboxylic acid
100578-69-6

phenanthrene-1,2-dicarboxylic acid

B

1,2,3,4-chrysenetetrone
125413-66-3

1,2,3,4-chrysenetetrone

Conditions
ConditionsYield
With KO2; 18-crown-6 ether In N,N-dimethyl-formamide for 20h; Ambient temperature;A 84 % Chromat.
B 8 % Chromat.
1-(trimethylsiloxy)-1,3-butadiene
63383-46-0

1-(trimethylsiloxy)-1,3-butadiene

benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

A

8-hydroxybenzo[b]chrysene-7,12-dione

8-hydroxybenzo[b]chrysene-7,12-dione

B

11-hydroxybenzo[b]chrysene-7,12-dione

11-hydroxybenzo[b]chrysene-7,12-dione

Conditions
ConditionsYield
Stage #1: 1-(trimethylsiloxy)-1,3-butadiene; benz-1,4-phenanthrenequinone In dichloromethane at -78 - 20℃; Diels-Alder reaction;
Stage #2: With jones reagent In acetone at 0 - 20℃; Jones oxidation; Title compound not separated from byproducts;
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride
72915-12-9

O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride

C32H14F10N2O2

C32H14F10N2O2

Conditions
ConditionsYield
In methanol at 20℃; for 24h;
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

1,4-dimethoxy-chrysene
109804-92-4

1,4-dimethoxy-chrysene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Na2S2O4; dioxane; SnCl2 / weitere Reagenzien: wss. HCl, Essigsaeure
View Scheme
benz-1,4-phenanthrenequinone
100900-16-1

benz-1,4-phenanthrenequinone

1,4-dihydroxy-chrysene-5,6-dione
130672-01-4

1,4-dihydroxy-chrysene-5,6-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: zinc-powder; pyridine
2: CrO3; Na2CrO4; acetic acid / Reagens 4: Acetanhydrid , Behandeln des Reaktionsprodukts mit wss.NaOH
View Scheme

100900-16-1Downstream Products

100900-16-1Relevant articles and documents

Improved synthesis of 1,4-phenanthrenequinones from Diels-Alder cycloadditions of 2-(p-Tolylsulfinyl)-1,4-benzoquinone

Carreno, M. Carmen,Mahugo, Jesus,Urbano, Antonio

, p. 3047 - 3050 (1997)

A wide range of substituted 1,4-phenanthrenequinones 5a-g and benz[c]- and benz[a]-1,4-phenanthrenequinones (5h) and (5i) were synthezised in one step through Diels-Alder cycloadditions of 2-(p-tolylsulfinyl)-1,4-benzoquinone 2 and vinylaromatic derivatives 1a-i under thermal and high pressure conditions in moderate to good yields (33-80%).

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