100903-77-3Relevant academic research and scientific papers
f-Element Complexes with Chelating Sulfur-Nitrogen-Ligands: Synthesis and Structure of 2UCl2
Knoesel, Friedrich,Noltemeyer, Mathias,Edelmann, Frank T.
, p. 1171 - 1174 (2007/10/02)
Li*0.5Et2O (1) is prepared by treatment of Me3SiNSNSiMe3 with phenyllithium.The lithium salt 1 reacts with UCl4, ScCl3(THF)3 and NdCl3(THF)2 to give di-, and trisubstituted complexes containing the chelating ligand. 2UCl (2) has been characterized by an X-ray structure determination. - Keywords: Sulfur-Nitrogen Ligands, Uranium, Scandium, Neodymium, Crystal Structure
