127161-27-7Relevant academic research and scientific papers
INORGANIC RING SYSTEMS CONTAINING LANTHANIDE ELEMENTS
Recknagel, Anja,Wedler, Michael,Knoesel, Friedrich,Edelmann, Frank T.
, p. 189 - 192 (2007/10/02)
Lanthanide complexes containing four-membered N-C-N-Ln, N-S-N-Ln and N-P-N-Ln rings have been synthesized by treatment of lanthanide halides with bulky anionic chelating ligands.Similar ring systems containing four different elements (N-Si-O-Ln) have been obtained by reacting anhydrous lanthanide trichlorides with LitBu)(NtBu)>.A twelve-membered inorganic ring is formed during the reaction of Cp*2Sm(THF)2 with 2.
f-Element Complexes with Chelating Sulfur-Nitrogen-Ligands: Synthesis and Structure of 2UCl2
Knoesel, Friedrich,Noltemeyer, Mathias,Edelmann, Frank T.
, p. 1171 - 1174 (2007/10/02)
Li*0.5Et2O (1) is prepared by treatment of Me3SiNSNSiMe3 with phenyllithium.The lithium salt 1 reacts with UCl4, ScCl3(THF)3 and NdCl3(THF)2 to give di-, and trisubstituted complexes containing the chelating ligand. 2UCl (2) has been characterized by an X-ray structure determination. - Keywords: Sulfur-Nitrogen Ligands, Uranium, Scandium, Neodymium, Crystal Structure
