1009034-08-5Relevant academic research and scientific papers
Interaction of dichloride iron(II) clathrochelate with dimercaptomaleodinitrile: Synthesis of the precursor monoribbed-functionalized phthalocyaninoclathrochelates and the unexpected formation of a new thiophene-containing heterocyclic system in the ribbed chelate fragment of the clathrochelate framework
Voloshin, Yan Z.,Varzatskii, Oleg A.,Belov, Alexander S.,Starikova, Zoya A.,Suponitsky, Kyrill Y.,Novikov, Valentin V.,Bubnov, Yurii N.
, p. 2155 - 2161 (2008)
Clathrochelate iron(II) FeBd2(S2C2(CN) 2Gm)(BF)2 tris-dioximate with a ribbed wodinitrile fragment was synthesized as a precursor of the monoribbed-functionalized hybrid phthalocyaninoclathrochelates by nucleophilic substitution of the vic-dichloride FeBd2(Cl2Gm)(BF)2 clathrochelate (1) with the potassium salt of dimercaptomaleodinitrile. Reaction of nitromethane with this salt was followed by the condensation of the reaction products with 1 to yield the clathrochelate with an annulated previously unknown thiazinothiophene heterocyclic system in the ribbed fragment. Both complexes were characterized on the basis of elemental analysis; MALDI-TOF mass spectrometry; IR, UV-vis, 57Fe Moessbauer, and NMR spectroscopies; and X-ray crystallography.
