100956-53-4Relevant academic research and scientific papers
Effects of Silver Carbonate and p-Nitrobenzoic Acid for Accelerating Palladium-Catalyzed Allylic C-H Acyloxylation
Skhiri, Aymen,Nagae, Haruki,Tsurugi, Hayato,Seki, Masahiko,Mashima, Kazushi
supporting information, p. 7044 - 7048 (2021/09/13)
An allylic C-H acyloxylation of terminal alkenes with 4-nitrobenzoic acid was assisted by a bidentate-sulfoxide-ligated palladium catalyst combined with 1,4-benzoquinone and Ag2CO3 under mild reaction conditions. The catalytic activity was remarkably enhanced by Ag2CO3 as an additive and 4-nitrobenzoic acid as a carboxylate source; both components were essential to exhibiting high catalytic activity, high branch selectivity, and a wide substrate scope with low loading of the palladium catalyst. Branch-selective allylic acyloxylation of ethyl 7-octenoate (1a) gave the product which was led to ethyl 6,8-dihydroxyoctanoate (5), a useful synthetic intermediate of (R)-α-lipoic acid.
Catalytic enantioselective allylic oxidation of olefins with copper(I) catalysts and new perester oxidants
Andrus, Merritt B.,Chen, Xi
, p. 16229 - 16240 (2007/10/03)
Asymmetric allylic oxidation of cyclic olefins using a catalytic amount of copper(I) bisoxazoline complexes and new peresters was investigated to give allylic benzoate esters in high selectivity (~80%ee), yield (70-80%), and at reasonable rates (5-7 d) at
