1009630-68-5

Upstream product

• 1009630-66-3 C₂₆H₃₂O₆S 
• 824-94-2 p-methoxybenzyl chloride 
• 131564-36-8 ethyl (S)-4,6-O-benzylidene-1-thio-β-D-galactopyranoside 

Downstream Products

• 1187765-97-4 ethyl 2-O-benzoyl-3-O-(para-methoxyphenyl)methyl-4:6-O-phenylmethylene-1-thio-β-D-galactopyranoside 
• 1441126-85-7 2,6-dimethylphenyl (2-azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-α-D-galactopyranosyl)-(1→3)-1-thio-4,6-O-benzylidene-2-deoxy-2-(2,2,2,-trichloroethoxycarbonylamino)-β-D-galactopyranoside 
• 1441128-86-4 2,6-dimethylphenyl (2-azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-galactopyranosyl)-(1→3)-1-thio-4,6-O-benzylidene-2-deoxy-2-(2,2,2,-trichloroethoxycarbonylamino)-β-D-galactopyranoside 
• 1441128-08-0 2-(trimethylsilyl)ethyl (2-O-benzyl-4,6-O-benzylidene-α-D-galactopyranosyl)-(1→4)-2-O-benzoyl-3,6-di-O-benzyl-β-D-galactopyranoside 
• 1441127-99-6 2-(trimethylsilyl)ethyl (2-O-benzyl-4,6-O-benzylidene-3-O-chloroacetyl-α-D-galactopyranosyl)-(1→4)-2-O-benzoyl-3,6-di-O-benzyl-β-D-galactopyranoside 
• 1441128-04-6 2-(trimethylsilyl)ethyl (2-O-benzyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-galactopyranosyl)-(1→4)-2-O-benzoyl-3,6-di-O-benzyl-β-D-galactopyranoside 
• 1441126-34-6 2-O-benzyl-4,6-O-benzylidene-3-O-chloroacetyl-α-D-galactopyranose 
• 1441128-90-0 2-O-benzyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-galactopyranose 
• 1441126-73-3 2,6-dimethylphenyl (2-O-benzyl-4,6-O-benzylidene-3-O-chloroacetyl-α-D-galactopyranosyl)-(1→4)-1-thio-2-O-benzoyl-3,6-di-O-benzyl-β-D-galactopyranoside 

Relevant academic research and scientific papers

Chemical synthesis of the tumor-associated globo H antigen

A derivative of the tumor-associated globo H antigen, a complex hexasaccharide, was synthesized by a convergent and efficient [3 + 2 + 1] strategy using various glycosylation methods. All glycosylation reactions afforded good to excellent yields and outst

Synthesis and biological evaluation of the Forssman antigen pentasaccharide and derivatives by a one-pot glycosylation procedure

The synthesis and biological evaluation of the Forssman antigen pentasaccharide and derivatives thereof by using a one-pot glycosylation and polymer-assisted deprotection is described. The Forssman antigen pentasaccharide, composed of GalNAcα(1,3)GalNAcβ(

First synthesis of a pentasaccharide repeating unit of the O-antigenic polysaccharide from enterohaemorrhagic Escherichia coli O48:H21

A concise synthesis of a pentasaccharide as its 4-methoxyphenyl glycoside, found in the O-antigenic polysaccharide of enterohaemorrhagic Escherichia coli O48:H21 has been achieved for the first time in excellent yield. Most of the intermediate steps are h

Remarkable solvent effect on Pd(0)-catalyzed deprotection of allyl ethers using barbituric acid derivatives: Application to selective and successive removal of allyl, methallyl, and prenyl ethers

Pd(0)-catalyzed deprotection of allyl ethers using barbituric acid derivatives in protic polar solvent such as MeOH and aqueous 1,4-dioxane proceeds at room temperature without affecting a wide variety of functional groups. Control of the reaction temperature allows selective and successive cleavage of allyl, methallyl, and prenyl ethers. A study of ligand effects on the deprotection reveals that the improved reactivity in MeOH results from the accelerated oxidative addition to Pd(O). Georg Thieme Verlag Stuttgart.