100990-22-5Relevant academic research and scientific papers
STEREOSELECTIVE SYNTHESIS OF ERYTHRO- AND THREO-1,2-DIOLS FROM DIKETO SULFIDES VIA CIS-3,4-DIHYDROXYTHIOLANES
Nakayama, Juzo,Yamaoka, Shoji,Hoshino, Masamatsu
, p. 1799 - 1802 (2007/10/02)
Intramolecular reductive coupling reaction of a series of diketo sulfides (1) by a low-valent titanium reagent at 0 deg C in tetrahydrofuran leads to cis-3,4-dihydroxythiolanes (2) exclusively in 67-89percent yields.Desulfurization of 2 by Raney nickel in
GENERAL SYNTHESIS OF POLYSUBSTITUTED THIOPHENES FROM DIKETO SULFIDES
Nakayama, Juzo,Machida, Haruki,Saito, Ryuji,Hoshino, Masamatsu
, p. 1983 - 1984 (2007/10/02)
Treatment of diketo sulfides with a low-valent titanium reagent at 0 deg C (in two cases at room temperature) affords 3,4-dihydroxythiolanes in good yields.The acid-catalyzed (p-toluenesulfonic acid) dehydration of the latter compounds leads to the corres
