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  • 101-01-9 Structure
  • Basic information

    1. Product Name: 1,2,3-TRIPHENYLGUANIDINE
    2. Synonyms: 1,2,3-trifenylguanidin;1,2,3-triphenyl-guanidin;n,n’,n’’-triphenyl-guanidin;N,N',N''-TRIPHENYLGUANIDINE;TRIPHENYLGUANIDINE;A-TRIPHENYLGUANIDINE;1,2,3-TRIPHENYLGUANIDINE;«
    3. CAS NO:101-01-9
    4. Molecular Formula: C19H17N3
    5. Molecular Weight: 287.36
    6. EINECS: 202-907-9
    7. Product Categories: N/A
    8. Mol File: 101-01-9.mol
    9. Article Data: 14
  • Chemical Properties

    1. Melting Point: 146-147°C
    2. Boiling Point: 419.66°C (rough estimate)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 1,16 g/cm3
    6. Refractive Index: 1.5800 (estimate)
    7. Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
    8. Solubility: N/A
    9. PKA: 9.10±0.10(Predicted)
    10. Water Solubility: Slightly soluble in water.
    11. CAS DataBase Reference: 1,2,3-TRIPHENYLGUANIDINE(CAS DataBase Reference)
    12. NIST Chemistry Reference: 1,2,3-TRIPHENYLGUANIDINE(101-01-9)
    13. EPA Substance Registry System: 1,2,3-TRIPHENYLGUANIDINE(101-01-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: 36/37/38-22
    3. Safety Statements: 26-36/37/39-36/37
    4. WGK Germany:
    5. RTECS: MF6825000
    6. TSCA: Yes
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 101-01-9(Hazardous Substances Data)

101-01-9 Usage

Description

1,2,3-Triphenylguanidine is an organic compound with the chemical formula C19H18N4. It is a white, crystalline powder that is combustible. 1,2,3-TRIPHENYLGUANIDINE is primarily used as an intermediate in organic synthesis and as an accelerator in the vulcanization of rubber.

Uses

Used in Organic Synthesis:
1,2,3-Triphenylguanidine is used as an intermediate for organic synthesis, serving as a building block for the development of various organic compounds and materials.
Used in Rubber Industry:
1,2,3-Triphenylguanidine is used as an accelerator for the vulcanization of rubber. It enhances the process by promoting the formation of cross-links between rubber molecules, resulting in improved strength, elasticity, and durability of the final rubber product.
Chemical Properties:
1,2,3-Triphenylguanidine is a white, crystalline powder with combustible properties. Its chemical structure and reactivity make it a valuable compound in various applications across different industries.

Purification Methods

Crystallise the guanidine from EtOH or EtOH/water. Dry it in vacuo.[Beilstein 12 H 451, 12 I 261, 12 II 246, 12 III 907, 12 IV 866.]

Check Digit Verification of cas no

The CAS Registry Mumber 101-01-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 1 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 101-01:
(5*1)+(4*0)+(3*1)+(2*0)+(1*1)=9
9 % 10 = 9
So 101-01-9 is a valid CAS Registry Number.

101-01-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (A18794)  N,N',N''-Triphenylguanidine, 97%   

  • 101-01-9

  • 5g

  • 310.0CNY

  • Detail
  • Alfa Aesar

  • (A18794)  N,N',N''-Triphenylguanidine, 97%   

  • 101-01-9

  • 25g

  • 1259.0CNY

  • Detail
  • Alfa Aesar

  • (A18794)  N,N',N''-Triphenylguanidine, 97%   

  • 101-01-9

  • 100g

  • 4251.0CNY

  • Detail

101-01-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,2,3-Triphenylguanidine

1.2 Other means of identification

Product number -
Other names N,N,N-Triphenylguanidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:101-01-9 SDS

101-01-9Relevant articles and documents

Novel Desulphurization of Thiourea Derivatives by Alkaline Autoxidation

Kim, Yong Hae,Kim, Hyung Jin,Yon, Gyu Hwan

, p. 1064 - 1065 (1984)

Autoxidation of 1,3-disubstituted thioureas in the presence of oxygen and tertiary butoxide in tertiary butanol afforded the corresponding ureas in good yields together with small amounts of the corresponding guanidines while the same treatment of benz- or naphth-imidazole-2-thiones gave the parent imidazoles and the 2-sulphonic acids.

-

Mc Creath

, p. 383 (1875)

-

-

Tieckelmann,Post

, p. 268,272 (1948)

-

O-Iodoxybenzoic acid mediated oxidative condensation: Synthesis of guanidines using 1,-3-disubstituted thiourea precursors

Dangate, Prasad S.,Akamanchi, Krishnacharya G.

, p. 6765 - 6767 (2013/01/15)

An efficient and mild oxidative condensation procedure using o-iodoxybenzoic acid and triethylamine or ammonia as base has been developed for the synthesis of guanidines starting from easily synthesizable 1,3-disubstituted thioureas and amines or ammonia.

Benzenetellurinic Mixed Anhydrides as Mild Oxidizing Agents

Fukumoto, Takahiro,Matsuki, Toshiaki,Hu, Nan Xing,Aso, Yoshio,Otsubo, Tetsuo,Ogura, Fumio

, p. 2269 - 2272 (2007/10/02)

Three benzenetellurinic mixed anhydrides. i. e. benzenetellurinyl acetate, trifluoroacetate, and trifluoromethanesulfonate, have been found to be mild oxidizing agents for various substrates such as thiol, phosphine, acyloin, α-hydroxy ester, catechol, hydroquinone, thiourea, and thioamide.The reactions towards the last two substrates are highly chemoselective, depending on both the reagent and substrate.

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