101011-90-9Relevant articles and documents
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McDonald,R.N.,Tabor,T.E.
, p. 2934 - 2941 (1968)
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Uemura,S. et al.
, p. 3702 - 3705 (1975)
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A Structurally Characterized Dichloro-manganese(IV) Complex Capable of Halogenating Alkenes
Law, Neil A.,Machonkin, Timothy E.,McGorman, Joel P.,Larson, Erlund J.,Kampf, Jeff W.,Pecoraro, Vincent L.
, p. 2015 - 2016 (2007/10/02)
MnIV(salpn)Cl2 regioselectively trans-halogenates alkenes in a reaction for which the Mn-containing product is also identified; this is the first Mn-based halogenating system for which the reactive and final Mn-containing products are structurally characterized.
Chlorination of alkenes with MnO2-MnCl2-acetyl chloride in dimethyl formamide
Bellesia,Ghelfi,Pagnoni,Pinetti
, p. 489 - 494 (2007/10/02)
Chlorination of alkenes was achieved in high yields by MnO2-MnCl2-acetyl chloride in dimethylformamide. A Mn(III) intermediate and a ligand-transfer process are suggested.