101028-25-5Relevant articles and documents
A general method for synthesis of cis-dicarbonyl epoxides through DBU/LiBr-cocatalyzed cyclization of α,β-dicarbonyl peroxides
Zong, Zhenzhen,Bai, Xiaohui,Lu, Shenglin,Li, Zhiping
supporting information, p. 3827 - 3831 (2016/08/02)
A general method for synthesis of cis-dicarbonyl epoxides is developed. The highly diastereoselective cyclization of α,β-dicarbonyl peroxides is achieved by DBU/LiBr cocatalysis. The coordination of lithium ion with two carbonyl groups is proposed for the
Photosensitized Oxidation of Furans. Part 13. Trapping Reactions of the Carbonyl Oxides Obtained from Some 2-Methoxy-5-phenylfurans
Graziano, M. Liliana,Iesce, M. Rosaria,Cimminiello, Guido,Scarpati, Rachele
, p. 1699 - 1704 (2007/10/02)
The dye-sensitized photo-oxygenation in methanol of the 2-methoxy-5-phenylfurans (1a-c), unsubstituted at C-4 with electron-withdrawing groups, leads to the hemiperacetals (4a-c).The reaction provides the first incontrovertible evidence for carbonyl oxide