101067-94-1

Basic information

• Product Name: Benzoic acid (R)-1-{(2R,3S)-2-[3-diazo-3-(4-nitro-benzyloxycarbonyl)-2-oxo-propyl]-4-oxo-azetidin-3-yl}-ethyl ester
• Synonyms: Benzoic acid (R)-1-{(2R,3S)-2-[3-diazo-3-(4-nitro-benzyloxycarbonyl)-2-oxo-propyl]-4-oxo-azetidin-3-yl}-ethyl ester
• CAS NO: 101067-94-1
• Molecular Weight: 480.434
• Mol File: 101067-94-1.mol

Chemical Properties

• CAS DataBase Reference: Benzoic acid (R)-1-{(2R,3S)-2-[3-diazo-3-(4-nitro-benzyloxycarbonyl)-2-oxo-propyl]-4-oxo-azetidin-3-yl}-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (R)-1-{(2R,3S)-2-[3-diazo-3-(4-nitro-benzyloxycarbonyl)-2-oxo-propyl]-4-oxo-azetidin-3-yl}-ethyl ester(101067-94-1)
• EPA Substance Registry System: Benzoic acid (R)-1-{(2R,3S)-2-[3-diazo-3-(4-nitro-benzyloxycarbonyl)-2-oxo-propyl]-4-oxo-azetidin-3-yl}-ethyl ester(101067-94-1)

Safety Data

• Hazardous Substances Data: 101067-94-1(Hazardous Substances Data)

Upstream product

• 93788-47-7 p-nitrobenzyl 2-diazo-3-(trimethylsilyl)oxy-3-butenoate 
• 101067-91-8 Benzoic acid (R)-1-((2R,3S)-2-acetyl-4-oxo-azetidin-3-yl)-ethyl ester 
• 101067-92-9 Benzoic acid (R)-1-((2S,3R)-2-acetoxy-4-oxo-azetidin-3-yl)-ethyl ester 
• 101067-90-7 Benzoic acid (R)-1-((3S,4R)-2-oxo-4-trimethylsilanylethynyl-azetidin-3-yl)-ethyl ester 
• 65-85-0 benzoic acid 

Downstream Products

• 101067-96-3 (5R,6S)-6-((R)-1-Benzoyloxy-ethyl)-3,7-dioxo-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 4-nitro-benzyl ester 

Relevant articles and documents

A FACILE, STEREOCONTROLLED ENTRY TO KEY INTERMEDIATES FOR THIENAMYCIN SYNTHESIS FROM ETHYL (S)-3-HYDROXYBUTANOATE

A new synthetic approach to optically active key intermediates for thienamycin synthesis is described which involves the highly stereocontrolled transformation of the 2-azetidinone obtained via the condensation of ethyl (S)-3-hydroxybutanoate with the N-s