101075-57-4

Basic information

• Product Name: {RhBr(CO)(CH₃C(CH₂P(C₆H₅)2)3)}
• CAS NO: 101075-57-4
• Molecular Weight: 835.502
• Mol File: 101075-57-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {RhBr(CO)(CH₃C(CH₂P(C₆H₅)2)3)}(CAS DataBase Reference)
• NIST Chemistry Reference: {RhBr(CO)(CH₃C(CH₂P(C₆H₅)2)3)}(101075-57-4)
• EPA Substance Registry System: {RhBr(CO)(CH₃C(CH₂P(C₆H₅)2)3)}(101075-57-4)

Safety Data

• Hazardous Substances Data: 101075-57-4(Hazardous Substances Data)

Upstream product

• 75070-58-5 {Rh(CO)2(triphos)}PF₆ 
• 1643-19-2 tetrabutylammomium bromide 
• 124223-20-7 [(CH₃C(CH₂PPh₂)3)Rh(CO)(H)] 
• 100-39-0 benzyl bromide 
• 14056-79-2 bromocarbonylbis(triphenylphosphine)rhodium(I) 

Relevant articles and documents

SOME RHODIUM(I) AND RHODIUM(III) COMPLEXES WITH THE TRIPOD-LIKE LIGANDS RC(CH2PPh2)3 (R=Me: triphos; R=Et: triphos-I) AND THE X-RAY CRYSTAL STRUCTURE OF

The syntheses of (8, triphos=CH3C(CH2PPh2)3) and the related compound (triphos-I=EtC(CH2PPh2)3) are described, and the X-ray crystal structure of the latter is reported.The crystals are monoclinic space group P21/a, a 15.985(6), b 19.683(7), c 11.900(4) Angstroem, β 103,73(6) degree, Z=4.The structure was solved by the heavy atom method and refined by full-matrix leastsquares to the conventional R factor value of 0.057 for 2649 observed reflections.The metal atom is octahedrally coordinated by three phophorus atoms and by three hydrogen atoms, each trans to one phosphorus.Complex 8 has been shown to react with CO to give (2).Compound 2 reacts with CH2=CHCO2Me to give only the branched insertion product .The complex has been re-investigated and was obtained in a single isomeric form which has been assigned a five-coordinate structure.The five-coordinate compounds (X=Br and I) are also described.