1010855-28-3

Basic information

• Product Name: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)AlCl(OSi(CH₃)3)
• CAS NO: 1010855-28-3
• Molecular Weight: 569.282
• Mol File: 1010855-28-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)AlCl(OSi(CH₃)3)(CAS DataBase Reference)
• NIST Chemistry Reference: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)AlCl(OSi(CH₃)3)(1010855-28-3)
• EPA Substance Registry System: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)AlCl(OSi(CH₃)3)(1010855-28-3)

Safety Data

• Hazardous Substances Data: 1010855-28-3(Hazardous Substances Data)

Upstream product

• 349545-04-6 Dipp₂nacnacAlCl₂ 
• 2004-14-0 lithium trimethylsilanolate 

Relevant articles and documents

Organoaluminum hydroxides supported by β-diketiminato ligands: Synthesis, structural characterization, and reactions

Three β-diketiminato ligands (L1 = HC[C(Me)N(Ar)] 2, Ar = 2,4,6-Me3C6H2; L2 = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H 3; L3 = HC[C(tBu)N(Ar)]2, Ar = 2,6iPr 2C6H3) were employed to prepare the organoaluminum hydroxides LAlR(OH) (R = Me, Et, Ph, OEt, OSiMe3) by hydrolysis of the corresponding chlorides in the presence of a N-heterocyclic carbene as HCl scavenger. Reaction of the organoaluminum hydroxide with Cp 2ZrMe2 in toluene afforded the heterobimetallic oxide LAlR(μ-O)ZrMeCp2 under evolution of methane. All compounds were characterized by multinuclear NMR, IR, mass spectrometry, and elemental analysis. The structures of L1AlPh(OH) (10), L2AlPh(OH) (11), L2AlOEt(OH) (12), L2AlOSiMe3(OH) (13), and L2AlPh(μ-O)ZrMeCp2 (17) were determined by single-crystal X-ray diffraction studies. The polymerization of ethylene was studied with compound 17, which exhibits moderate catalytic activity.