349545-04-6

Basic information

• Product Name: Dipp₂nacnacAlCl₂
• Synonyms: Dipp₂nacnacAlCl₂
• CAS NO: 349545-04-6
• Molecular Weight: 515.545
• Mol File: 349545-04-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Dipp₂nacnacAlCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: Dipp₂nacnacAlCl₂(349545-04-6)
• EPA Substance Registry System: Dipp₂nacnacAlCl₂(349545-04-6)

Safety Data

• Hazardous Substances Data: 349545-04-6(Hazardous Substances Data)

Upstream product

• 7446-70-0 aluminium trichloride 
• 334719-92-5 Dipp₂nacnacLi*Et₂O 

Downstream Products

• 1010855-33-0 (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Al(OSi(CH₃)3)(OH) 
• 1018986-36-1 HC[C(Me)N(2,6-iPr₂C₆H₃)]2Al(F)NMe₂ 
• 1018986-34-9 HC[C(Me)N(2,6-iPr₂C₆H₃)]2Al(Me)NMe₂ 
• 934009-05-9 HC[(CMe)(N-2,6-iPr₂C₆H₃)]2Al(OH)(OEt) 
• 1010855-28-3 (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)AlCl(OSi(CH₃)3) 
• 1010855-27-2 (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)AlCl(OC₂H₅) 
• 1018986-28-1 HC[C(Me)N(2,6-iPr₂C₆H₃)]2Al(Cl)NMe₂ 
• 705263-87-2 [(CH(C(CH₃)N(C₆H₃(CH(CH₃)2)2))2)Al(NH₂)2] 
• 552812-70-1 (HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)Al(OH)2 
• 1227501-98-5 (2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)Al(NHEt)2 

Relevant articles and documents

A Well-Defined Aluminum-Based Lewis Acid as an Effective Catalyst for Diels-Alder Transformations

A catalytically active aluminum-based system for Diels-Alder transformations is reported. The system was generated by mixing a β-diketiminate-stabilized aluminum bistriflate compound with Na[BArCl4] (ArCl=3,5-Cl2C6H3). Solid-state analysis of the catalytic system reveals a unique structure incorporating a two-dimensional coordination polymer. According to the experimental results obtained from several Diels-Alder transformations, the aluminum-based system appears to be a more practical and more robust alternative to the recently reported compounds based on carbon and silicon cations.