1011458-58-4

Basic information

• Product Name: ethyl 2-[(2-benzyloxycarbonylmethyl-5-bromo)phenyl]-2-(phenylthio)acetate
• Synonyms: ethyl 2-[(2-benzyloxycarbonylmethyl-5-bromo)phenyl]-2-(phenylthio)acetate
• CAS NO: 1011458-58-4
• Molecular Weight: 499.425
• Mol File: 1011458-58-4.mol

Chemical Properties

• CAS DataBase Reference: ethyl 2-[(2-benzyloxycarbonylmethyl-5-bromo)phenyl]-2-(phenylthio)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-[(2-benzyloxycarbonylmethyl-5-bromo)phenyl]-2-(phenylthio)acetate(1011458-58-4)
• EPA Substance Registry System: ethyl 2-[(2-benzyloxycarbonylmethyl-5-bromo)phenyl]-2-(phenylthio)acetate(1011458-58-4)

Safety Data

• Hazardous Substances Data: 1011458-58-4(Hazardous Substances Data)

Upstream product

• 1011458-32-4 benzyl 2-(4-bromophenyl)-2-diazoacetate 
• 7605-25-6 ethyl phenylsulfenylacetate 

Relevant articles and documents

Rh(II)-catalyzed Sommelet-Hauser rearrangement

Catalytic Sommelet-Hauser rearrangement is reported. The Rh(II)-catalyzed reaction of aryldiazoacetates with ethyl benzylthioacetate affords Sommelet-Hauser rearrangement products in good to excellent yields. This reaction provides a reliable and efficient way to introduce a substituent to the ortho position of arylacetates.