1011458-32-4Relevant articles and documents
Preparation of Organic Nitrates from Aryldiazoacetates and Fe(NO3)3·9H2O
Thurow, Samuel,Fernandes, Alessandra A. G.,Quevedo-Acosta, Yovanny,De Oliveira, Matheus F.,De Oliveira, Marcelo G.,Jurberg, Igor D.
, p. 6909 - 6913 (2019)
A thermal protocol is reported for the formal insertion of nitric acid into aryldiazoacetates using Fe(NO3)3·9H2O. This strategy is mild and high yielding and allows the preparation of a large variety of members of an unprecedented family of organic nitrates. The nitrate group can be also readily transformed into other functional groups and heterocyclic moieties and can possibly allow new biological explorations of untapped potential associated with their NO-releasing ability.
Enantioselective preparation of cis -β-azidocyclopropane esters by cyclopropanation of azido alkenes using a chiral dirhodium catalyst
Gu, Peiming,Su, Yan,Wu, Xiu-Ping,Sun, Jian,Liu, Wanyi,Xue, Ping,Li, Rui
supporting information; experimental part, p. 2246 - 2249 (2012/06/30)
A diastereo- and enantiocontrolled preparation of the conformationally restricted cis-β-azidocyclopropane esters have been developed. The Rh 2(S-DOSP)4 was found to be an efficient catalyst in hexane for the cyclopropanation of azido