101220-62-6Relevant articles and documents
Metal-Free Difluoromethylselenolation of Arylamines under Visible-Light Photocatalysis
Lu, Kui,Li, Quan,Xi, Xiaolan,Zhou, Ting,Zhao, Xia
, p. 1224 - 1231 (2020)
A novel visible-light photocatalytic difluoromethylselenolation of aryl amines via in situ generation of aryldiazonium salts was achieved using Se-(difluoromethyl) 4-methylbenzenesulfonoselenoate, which was synthesized for the first time. The reagent is readily accessible and shelf-stable. The metal-free reaction conditions and the broad substrate scope provide a green protocol for the efficient and rapid introduction of the difluoromethylselenylether group.