1012859-65-2

Basic information

• Product Name: C₁₃H₁₄ClNO₄
• Synonyms: C₁₃H₁₄ClNO₄
• CAS NO: 1012859-65-2
• Molecular Weight: 283.711
• Mol File: 1012859-65-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₄ClNO₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₄ClNO₄(1012859-65-2)
• EPA Substance Registry System: C₁₃H₁₄ClNO₄(1012859-65-2)

Safety Data

• Hazardous Substances Data: 1012859-65-2(Hazardous Substances Data)

Upstream product

• 104-86-9 4-chlorobenzylamine 
• 762-42-5 dimethyl acetylenedicarboxylate 

Downstream Products

• 1450999-78-6 dimethyl 1-(4-chlorobenzyl)-4,6,6-triphenyl-1,6-dihydropyridine-2,3-dicarboxylate 

Relevant articles and documents

Photocatalytic Visible-Light-Induced Nitrogen Insertion via Dual C(sp3)-H and C(sp2)-H Bond Functionalization: Access to Privileged Imidazole-based Scaffolds

Here we have demonstrated a visible-light-mediated metal-free organic-dye-catalyzed dehydrogenative N-insertion leading to highly substituted imidazoles and privileged dihydroisoquinoline-based imidazole derivatives via C(sp3)-H and C(sp2)-H bond functionalization. A sustainable, convenient, metal-free azidation/C-H aminative cyclization approach in the absence of stoichiometric oxidants is presented. This protocol involves a rare photoinduced iminyl radical as a key intermediate for the "N"insertion.

Lewis acid-promoted cascade reaction of primary amine, 2-butynedioate, and propargylic alcohol: A convenient approach to 1,2-dihydropyridines and 1H-pyrrolo[3,4-b]pyridine-5,7(2H,6H)-diones

1,2-Dihydropyridine-5,6-dicarboxylates were efficiently constructed through a cascade reaction of primary amine, 2-butynedioate and propargylic alcohol in the presence of Lewis acid under mild conditions. As exceptional, 1H-pyrrolo[3,4-b]pyridine-5,7(2H,6