10129-07-4

Basic information

• Product Name: ETHYL 4-PHENYLSULFANYLBENZOATE
• Synonyms: ETHYL 4-PHENYLSULFANYLBENZOATE
• CAS NO: 10129-07-4
• Molecular Formula: C₁₅H₁₄O₂S
• Molecular Weight: 258.34
• Mol File: 10129-07-4.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 163 °C(Press: 1 Torr)
• Appearance: /
• Density: 1.19±0.1 g/cm3(Predicted)
• CAS DataBase Reference: ETHYL 4-PHENYLSULFANYLBENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 4-PHENYLSULFANYLBENZOATE(10129-07-4)
• EPA Substance Registry System: ETHYL 4-PHENYLSULFANYLBENZOATE(10129-07-4)

Safety Data

• Hazardous Substances Data: 10129-07-4(Hazardous Substances Data)

Upstream product

• 7335-27-5 ethyl 4-chlorobenzoate 
• 882-33-7 diphenyldisulfane 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 16906-70-0 phenyl N,N-dimethyl dithiocarbamate 
• 94-09-7 p-aminoethylbenzoate 
• 108-98-5 thiophenol 
• 261516-38-5 (4-(ethoxycarbonyl)phenyl)zinc chloride 
• 14204-27-4 N-phenylthiophthalimide 
• 51934-41-9 4-iodobenzoic acid ethyl ester 
• 591-50-4 iodobenzene 
• 20057-83-4 diethyl 4,4'-dithiobis 
• 5798-75-4 Ethyl 4-bromobenzoate 
• 82102-37-2 9-methyl-9H-fluorene-9-carbonyl chloride 
• 4551-15-9 phenylthiotrimethylsilane 

Downstream Products

• 1258780-20-9 4-ethoxycarbonylphenyl(phenyl)sulfoxide 
• 77868-25-8 4-(phenylthio)benzohydroxamic acid 
• 100866-34-0 p-Phenylmercapto-N-methylbenzamid 
• 6310-24-3 4-(phenylthio)benzoic acid 

Relevant articles and documents

Simple and efficient copper-catalyzed S-arylation of diaryl disulfides with triarylbismuthanes under aerobic conditions

Novel and simple copper-catalyzed C(aryl)-S bond formation of diaryl disulfides with bismuth reagents is described. Reactions of diaryl disulfides with triarylbismuthanes in the presence of CuOAc (10 mol %) and 1,10-phenanthroline (10 mol %) under aerobic conditions led to the formation of unsymmetrical diaryl sulfides in satisfactory yields. The reaction is atom-economic and all three aryl groups of the triarylbismuthanes and both sulfanyl groups of the diaryl disulfides could be transferred to the coupling products.

Iron-catalyzed thioetherification of thiols with aryl iodides

FeCl3 in combination with bisphosphine ligands represents an efficient catalyst system for the cross-coupling of aryl- and alkyl thiols with aryl iodides, a broad spectrum of functional groups can be tolerated during the catalysis. The Royal Society of Chemistry 2009.

Aryldithiocarbamates as thiol alternatives in Cu-catalyzed C(aryl)-S coupling reactions using aryldiazonium tetrafluoroborate salts

An efficient method for the synthesis of unsymmetrical diaryl sulfides has been developed by the C-S cross coupling of aryldithiocarbamates and aryldiazonium salts in the presence of CuI-2,2′-bipyridine and Zn. Aryldithiocarbamate compounds have been used here as thiol substitutes. The protocol shows wide substrate scope and good yields of the products.

Copper-Catalyzed Electrophilic Thiolation of Organozinc Halides by Using N-Thiophthalimides Leading to Polyfunctional Thioethers

(Hetero)aryl, benzylic, and alkyl zinc halides were thiolated with N-thiophthalimides at 25 °C within 1 h in the presence of 5–10 % Cu(OAc)2?H2O to furnish the corresponding polyfunctionalized thioethers in good yields. This electrop