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101329-85-5

1-(phenylthio)cyclobutanecarbonitrile is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 101329-85-5 Structure

  • Basic information

    1. Product Name: 1-(phenylthio)cyclobutanecarbonitrile
    2. Synonyms: 1-(phenylthio)cyclobutanecarbonitrile
    3. CAS NO:101329-85-5
    4. Molecular Formula:
    5. Molecular Weight: 189.281
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 101329-85-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1-(phenylthio)cyclobutanecarbonitrile(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1-(phenylthio)cyclobutanecarbonitrile(101329-85-5)
    11. EPA Substance Registry System: 1-(phenylthio)cyclobutanecarbonitrile(101329-85-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 101329-85-5(Hazardous Substances Data)

101329-85-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 101329-85-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,1,3,2 and 9 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 101329-85:
(8*1)+(7*0)+(6*1)+(5*3)+(4*2)+(3*9)+(2*8)+(1*5)=85
85 % 10 = 5
So 101329-85-5 is a valid CAS Registry Number.

101329-85-5Relevant articles and documents

Transition-metal-free decarboxylative thiolation of stable aliphatic carboxylates

Xing, Wei-Long,Liu, De-Guang,Fu, Ming-Chen

, p. 4593 - 4597 (2021/02/03)

A transition-metal-free decarboxylative thiolation protocol is reported in which primary, secondary, tertiary (hetero)aryl acetates and α-CN substituted acetates undergo the decarboxylative thiolation smoothly, to deliver a variety of functionalized aryl alkyl sulfides in moderate to excellent yields. Aryl diselenides are also amenable substrates for construction of C-Se bonds under the simple and mild reaction conditions. Moreover, the protocol is successfully applied to the late-stage modification of pharmaceutical carboxylates with satisfactory chemoselectivity and functional-group compatibility. This journal is

Arylthio-metal exchange of α-arylthioalkanenitriles

Nath, Dinesh,Skilbeck, Melanie C.,Coldham, Iain,Fleming, Fraser F.

supporting information, p. 62 - 65 (2014/01/23)

The addition of BuLi, Bu3MgLi, Et2ZnBuLi, or Me 2CuLi to α-arylthioalkanenitriles triggers an arylthio-metal exchange. NMR spectroscopic analyses implicate organometallic attack on sulfur forming a three-coordinate sulfidate as the key intermediate. Electrophilic trapping affords tertiary and quaternary nitriles in high yield. The method addresses the challenge of improving the functional group tolerance and preventing polyalkylations.

Sulfinylnitriles: Sulfinyl-metal exchange-alkylation strategies

Nath, Dinesh,Fleming, Fraser F.

supporting information, p. 2023 - 2029 (2013/03/14)

Adding organolithiums, Grignard reagents, or zincates to sulfinylnitriles triggers a facile sulfinyl-metal exchange to afford N- or C-metalated nitriles. Sulfinyl-magnesium exchange-alkylations efficiently install quaternary and tertiary centers, even in

Nitrile alkylations through sulfinyl-metal exchange

Nath, Dinesh,Fleming, Fraser F.

supporting information; experimental part, p. 11790 - 11793 (2012/01/06)

Triple alkylation: Phenylsulfinyl- and phenylthioacetonitrile can function as trianion equivalents of acetonitrile by sequential alkylation and sulfinyl-metal exchange (see scheme; mCPBA=meta-chloroperoxybenzoic acid). The metalated nitriles alkylate a range of electrophiles to obtain nitriles with quaternary centers. The sulfinyl-metal exchange proceeds under very mild conditions and has a high functional-group tolerance. Copyright

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