101342-37-4Relevant articles and documents
Crystal and Molecular Structure of a Dioxo-molybdenum Phosphorus-substituted Alkylidene resulting from the First Observed Aryl Migration from Molybdenum to Carbon
Arzoumanian, Henri,Baldy, Andre,Lai, Richard,Metzger, Jacques,Peh, Marie-Louise Nkeng,Pierrot, Marcel
, p. 1151 - 1152 (1985)
The reaction of Mo(O)2(mesityl)2 with Bu3PCH2 yields (mesityl)(O)2Mo=C(mesityl)PBu3, the first example of a dioxo-metal phosphorus-substituted carbene resulting from a double α-hydrogen abstraction and aryl migration from molybdenum to carbon within the co-ordination sphere of the metal.