29218-85-7Relevant academic research and scientific papers
Three novel anions based on pentafluorophenyl amine combined with two new synthetic strategies for the synthesis of highly lipophilic ionic liquids
Linder, Thomas,Sundermeyer, Joerg
supporting information; experimental part, p. 2914 - 2916 (2009/12/01)
The three new fluorinated anions BPFPA, PFTFSI, and PFNFSI for highly hydrophobic, hydrolytically stable ionic liquids are introduced, together with a strategy allowing a combinatorial approach for the synthesis of imidazolium and phosphonium based ionic
ACTION DU METHYLTRI(N-BUTYL)FLUOROPHOSPHORANE SUR LES HALOGENURES ET LES SULFONATES D'ALKYLE
Leroy, J.,Bensoam, J.,Humiliere, M.,Wakselman, C.,Mathey, F.
, p. 1931 - 1936 (2007/10/02)
Monofluorophosphoranes R3MePF are used in exchange reactions to prepare monofluorinated organic compounds.Tri(n-butyl)methylfluorophosphorane (n-Bu3MePF), easily available, is the most reactive.In solvents of low polarity or even in non-polar solvents, it reacts at -70 deg C with alkyl sulphonates and halides activated by ester, ketone, or ether functions.Thus, fluorinated epoxides can be obtained directly by exchange from their chlorinated or brominated homologues.
