10138-59-7Relevant articles and documents
CATALYTIC SYNTHESIS OF N-ALKYLOCTAHYDROISOINDOLES
Kozintsev, S. I.,Zhavrid, A. S.,Serzhanin, A. I.,Kozlov, N. S.
, p. 1346 - 1348 (1990)
Catalytic hydroamination of 1,2-bis(hydroxymethyl)cyclohexane by aliphatic nitriles over a nickel catalyst yielded a series of N-alkyl-substituted octahydroisoindoles.Conditions for their synthesis were selected.The IR, PMR, and mass spectra and the proba
Recyclable cobalt(0) nanoparticle catalysts for hydrogenations
Büschelberger, Philipp,Reyes-Rodriguez, Efrain,Sch?ttle, Christian,Treptow, Jens,Feldmann, Claus,Jacobi Von Wangelin, Axel,Wolf, Robert
, p. 2648 - 2653 (2018/05/30)
The search for new hydrogenation catalysts that replace noble metals is largely driven by sustainability concerns and the distinct mechanistic features of 3d transition metals. Several combinations of cobalt precursors and specific ligands in the presence of reductants or under high-thermal conditions were reported to provide active hydrogenation catalysts. This study reports a new method of preparation of small, monodisperse Co(0) nanoparticles (3-4 nm) from the reduction of commercial CoCl2 in the absence of ligands or surfactants. High catalytic activity was observed in hydrogenations of alkenes, alkynes, imines, and heteroarenes (2-20 bar H2). The magnetic properties enabled catalyst separation and multiple recyclings.
PROCESS FOR HYDROGENATION OF POLYCARBOXYLIC ACIDS OR DERIVATIVES THEROF
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Paragraph 0041; 0042; 0043, (2013/06/27)
The disclosure provides a process for hydrogenation of polycarboxylic acids or derivatives thereof, including: hydrogenation of polycarboxylic acids or derivatives thereof in the presence of a catalyst, wherein the catalyst includes an active metal and a
