101488-73-7Relevant articles and documents
Thin film field-effect transistors of 2,6-diphenyl anthracene (DPA)
Liu, Ji,Dong, Huanli,Wang, Zongrui,Ji, Deyang,Cheng, Changli,Geng, Hua,Zhang, Hantang,Zhen, Yonggang,Jiang, Lang,Fu, Hongbing,Bo, Zhishan,Chen, Wei,Shuai, Zhigang,Hu, Wenping
, p. 11777 - 11779 (2015)
An anthracene derivative, 2,6-diphenyl anthracene (DPA), was successfully synthesized with three simple steps and a high yield. The compound was determined to be a durable high performing semiconductor with thin film device mobility over 10 cm2
Synthesis of Enantiopure C2-Symmetric Anthracenophane and Dimerization en Route to Multiple-Bridged Cyclophanes
Ohmori, Ken,Suzuki, Keisuke,Ueda, Yasuyuki
, (2020)
We report the stereocontrolled synthesis of enantiopure C2-symmetric anthracenophanes and their derivatization to D2-symmetric multiple-bridged cyclophanes via photoinduced [4 + 4] dimerization.
π-Extended Indenofluorenes
Rao, M. Rajeswara,Desmecht, Antonin,Perepichka, Dmitrii F.
, p. 6193 - 6201 (2015)
A series of π-extended aromatic indenofluorene (IF) analogues with naphthalene and anthracene cores have been synthesized through acid-catalyzed intramolecular cyclization. The regioselectivity of the reaction is controlled by a combination of steric and
Exploring the relation between amplification and binding in dynamic combinatorial libraries of macrocyclic synthetic receptors in water
Corbett, Peter T.,Sanders, Jeremy K.M.,Otto, Sijbren
, p. 2153 - 2166 (2008)
Herein we describe an extensive study of the response of a set of closely related dynamic combinatorial libraries (DCLs) of macrocyclic receptors to the introduction of a focused range of guest molecules. We have determined the amplification of two sets of diastereomeric receptors induced by a series of neutral and cationic guests, including biologically relevant compounds such as acetylcholine and morphine. The host-guest binding affinities were investigated using isothermal titration calorimetry. The resulting dataset enabled a detailed analysis of the relationship between the amplification of selected receptors and host-guest Gibbs binding energies, giving insight into the factors affecting the design, simulation and interpretation of DCL experiments. In particular, two questions were addressed: Is amplification by a given guest selective for the best receptor? And does the best guest induce the largest amplification of a given receptor? Our experimental results and computer simulations showed that the relative levels of amplification of hosts by a guest are well-correlated with their relative affinities, and simulations have confirmed previous observations that amplification can be selective for the best receptor when only modest amounts of guest are used. In contrast, the correlation between guest binding and the extent of amplification of a given receptor across a wide range of guests tends to be poorer, because every guest has its own unique set of affinities for competing receptors in the DCL. This implies that the results of screening a DCL for selective receptors by comparing the response of the mixture to two different guests should be interpreted with caution. DCLs are complex mixtures in which all compounds are connected through a set of equilibria. Obtaining quantitative information about all host-guest binding constants from such systems will require the explicit and simultaneous consideration of all of the main equilibria within a DCL.
Substitution site effect of naphthyl substituted anthracene derivatives and their applications in organic optoelectronics
Chen, Mingxi,Dang, Yangyang,Dong, Huanli,Hu, Wenping,Hu, Yongxu,Ji, Deyang,Li, Jie,Li, Liqiang,Liu, Jinyu,Qin, Zhengsheng,Sun, Yajing,Zhen, Yonggang
, p. 15597 - 15602 (2020)
By introducing the naphthyl group into the 2,6-positions of anthracene, two different anthracene derivatives, 2,6-di(2-naphthyl)anthracene (2,6-di(2-Na)Ant) and 2,6-di(1-naphthyl)anthracene (2,6-di(1-Na)Ant) were synthesized. The tiny change in the substitution site of the naphthyl group leads to a significant difference in the molecular packing and further exerts a great impact on their optoelectronic properties. Thin film field-effect transistors for 2,6-di(2-Na)Ant show charge transport mobility up to 2.1 cm2 V-1 s-1, while 2,6-di(1-Na)Ant demonstrates no mobility. Moreover, thin film phototransistors of 2,6-di(2-Na)Ant show a photoresponsivity of 6.9 × 103 A W-1, a high photosensitivity of 2.6 × 106 and an excellent detectivity of 3.4 × 1016 Jones, which is one of the highest performances of thin film organic phototransistors reported to date. This journal is
A new asymmetric anthracene derivative with high mobility
Yu, Xixia,Zheng, Lei,Li, Jinfeng,Wang, Lu,Han, Jiangli,Chen, Huayi,Zhang, Xiaotao,Hu, Wenping
, p. 251 - 255 (2019/01/14)
An asymmetric anthracene derivative (4-HDPA) was designed and synthesized. With the optimization of proper scenario of fabrication process, top-contact thin film devices based on 4-HDPA exhibit mobility as high as 3.59 cm2 V–1 s
