1015-27-6

Basic information

• Product Name: Stannane, triethyl(phenylethynyl)-
• CAS NO: 1015-27-6
• Molecular Formula: C14H20Sn
• Molecular Weight: 307.023
• Mol File: 1015-27-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Stannane, triethyl(phenylethynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, triethyl(phenylethynyl)-(1015-27-6)
• EPA Substance Registry System: Stannane, triethyl(phenylethynyl)-(1015-27-6)

Safety Data

• Hazardous Substances Data: 1015-27-6(Hazardous Substances Data)

Upstream product

• 1004-22-4 phenylethynylsodium 
• 660-74-2 diethyl tin 
• 994-32-1 triethyltin hydroxide 
• 536-74-3 phenylacetylene 
• 6738-06-3 phenylethynylmagnesium bromide 
• 15239-24-4 Triethylsilyloxy-triethyl-stannan 
• 997-50-2 triethylstannane 
• 17316-41-5 Si-Trimethyl-Sn-triethyl-stannosiloxan 
• 994-31-0 chlorotriethylstannane 
• 1004-22-4 (phenylethynyl)sodium 
• 1112-63-6 hexaethyldistannoxane 
• 1067-21-6 triethylmethoxystannane 
• 17545-03-8 Triethyl-[3-(2-vinyloxy-ethoxy)-prop-1-ynyl]-stannane 
• 4554-88-5 Acetic acid triethylstannanylmethyl ester 

Downstream Products

• 1247-08-1 Triphenyl-phenylethynyl-stannane 
• 994-31-0 chlorotriethylstannane 
• 21301-75-7 (C₂H₅)3SnC(C₆H₅)(C₁₅H₁₀N₂O₂) 
• 994-32-1 triethyltin hydroxide 
• 597-64-8 tetraethyltin 
• 994-39-8 triethylethynylstannane 
• 1907-13-7 acetoxytriethylstannane 
• 19752-26-2 (C₂H₅)3SnCH₂CHCHC₆H₅ 
• 24850-38-2 (C₂H₅)3SnCH₂CH₂CHCHC₆H₅ 
• 21249-45-6 3,4,6-triphenyl-5-triphenylstannylpyridazine 
• 24602-53-7 (C₆H₅)3SnC₃H₂N₂(C₆H₅) 
• 78629-82-0 cis-[Pt(C_.tplbond.CPh)(SnEt₃)(PPh₃)2] 
• 78629-82-0 Pt(C₆H₅C₂Sn(C₂H₅)3)(P(C₆H₅)3)2 
• 78629-82-0 ((C₆H₅)3P)2Pt(Sn(C₂H₅)3)(CCC₆H₅) 

Relevant articles and documents

Catalytic Dehydrogenative Stannylation of C(sp)-H Bonds Involving Cooperative Sn-H Bond Activation of Hydrostannanes

The catalytic generation of a stannylium-ion-like tin electrophile by heterolytic cleavage of the Sn-H bond in hydrostannanes at the Ru-S bond of Ohki-Tatsumi complexes is reported. Reacting these activated hydrostannanes with terminal acetylenes does not lead to hydrostannylation of the C-C triple bond but to dehydrogenative stannylation of the alkyne terminus. The scope of this rare direct C(sp)-H bond stannylation with hydrostannanes is broad, and a mechanism involving a β-tin-stabilized vinyl cation likely having a bridged structure is presented.