1015066-14-4Relevant articles and documents
Reactivity of cis-{PtII(Ar)(alkyne)} fragments (Ar = aryl): A domino-formation of indenes
Cucciolito, Maria Elena,De Renzi, Augusto,Roviello, Giuseppina,Ruffo, Francesco
, p. 1351 - 1353 (2008)
The reactivity of cis-{PtII(Ar)(2-butyne)] fragments in cationic complexes is described. Coordination of the unsaturated ligand is observed at low temperature. Upon increasing at 298 K, a cascade of reactions affords a selective formation of indenes. Mechanistic implications of this domino-reaction are discussed.