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14104-20-2

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Silver tetrafluoroborate
Cas No: 14104-20-2
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Silver Tetrafluoroborate with high purity
Cas No: 14104-20-2
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silver tetrafluoroborate
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Amadis Chemical offer CAS#14104-20-2;CAT#A807720
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Silver tetrafluoroborate
Cas No: 14104-20-2
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Hot sale 14104-20-2 Silver tetrafluoroborate with best price
Cas No: 14104-20-2
USD $ 1000.0-1500.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Hebei Guanlang Biotechnology Co., Ltd. Contact Supplier
Silver tetrafluoroborate /high quality
Cas No: 14104-20-2
USD $ 6.0-6.0 / Kilogram 1 Kilogram 100 Kilogram/Week Career Henan Chemical Co Contact Supplier
Silver(I) tetrafluoroborate
Cas No: 14104-20-2
No Data No Data 5 Hangzhou J&H Chemical Co., Ltd. Contact Supplier
High Purity Silver Tetrafluoroborate
Cas No: 14104-20-2
No Data 1 Kilogram 2000 Metric Ton/Year Xiamen BaiFuchem Co.,Ltd Contact Supplier
Silver tetrafluoroborate
Cas No: 14104-20-2
No Data 1 Kilogram 1000 Kilogram/Month Hebei Zhuangkai Biotechnology Co.,Ltd Contact Supplier

14104-20-2 Usage

Uses

Gold Catalysts — 21st Century ′Gold Rush′

Chemical Properties

beige crystalline powder

Uses

Displaces chloride from metal complexes.
InChI:InChI=1/8Ag.4BFO2/c;;;;;;;;4*2-1(3)4/q8*+1;4*-2

14104-20-2 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (208361)  Silvertetrafluoroborate  98% 14104-20-2 208361-50G 5,316.48CNY Detail
Aldrich (208361)  Silvertetrafluoroborate  98% 14104-20-2 208361-10G 1,278.81CNY Detail
Aldrich (208361)  Silvertetrafluoroborate  98% 14104-20-2 208361-1G 297.18CNY Detail
Aldrich (483052)  Silvertetrafluoroborate  ≥99.99% trace metals basis 14104-20-2 483052-25G 6,557.85CNY Detail
Aldrich (483052)  Silvertetrafluoroborate  ≥99.99% trace metals basis 14104-20-2 483052-5G 1,845.09CNY Detail
Alfa Aesar (11539)  Silver tetrafluoroborate, 99%    14104-20-2 50g 3873.0CNY Detail
Alfa Aesar (11539)  Silver tetrafluoroborate, 99%    14104-20-2 10g 1087.0CNY Detail

14104-20-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Silver Tetrafluoroborate

1.2 Other means of identification

Product number -
Other names silver,tetrafluoroborate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14104-20-2 SDS

14104-20-2Synthetic route

silver fluoride

silver fluoride

trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In diethyl ether BF3*C2H5OC2H5 was aded to a suspn. of AgF in diethyl ether, stirred until a clear soln. was obtained; the solvent was removed in vac.;89.7%
In not given
hydrogen fluoride
7664-39-3

hydrogen fluoride

boron trifluoride
7637-07-2

boron trifluoride

silver nitrate

silver nitrate

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
solvation of AgNO3 in HF not above 0°C under stirring and introduction of BF3;; precipitation; washing with liquid HF and drying in a stream of N2 (12 hours), later in vacuum (12 hours);;85%
In hydrogen fluoride react. mechanism discussed;;
In hydrogen fluoride HF (liquid); react. mechanism discussed;;
In hydrogen fluoride HF (liquid); High Pressure; in FEP vessel liquid HF was condensed onto AgNO3 at 77 K and warmed to room temp., BF3 was added for 12 h (2 bar); liquid phase was decanted, residue was dried by pumping for 3 h; X-ray powder diffraction;
boron trifluoride
7637-07-2

boron trifluoride

xenon

xenon

silver fluoride

silver fluoride

fluorine
7782-41-4

fluorine

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

xenon difluoride
13709-36-9

xenon difluoride

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); treatment AgF with BF3 in HF, pptn. of AgBF4, adnn. of F2, removal of volatiles, addn. of Hf, BF3 and xenon (condensed in reactor, -100°C), warming to 20°C with stirring (thermal cycling repeated 3-4 times, in 2 h); removal of volatile (vac., -45°C, 5 h), XeF2 (U trap, -78°C); x-ray photography;A n/a
B 66%
silver(II) fluoride

silver(II) fluoride

boron trifluoride
7637-07-2

boron trifluoride

xenon

xenon

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

xenon difluoride
13709-36-9

xenon difluoride

Conditions
ConditionsYield
With HF In hydrogen fluoride HF (liquid); mixing of AgF2 and BF3 in HF (-100°C), warming(to room temp., stirring), addn. of xenon (stirring 12 h); removal of volatile (-45°C, vac.), XeF2 (U trap, -78°C); x-ray powder photography and Raman spectroscopy; novolatile AgBF4; x-ray powder photography;A n/a
B 57.9%
silver(l) oxide
20667-12-3

silver(l) oxide

tetrafluorohydroboric acid

tetrafluorohydroboric acid

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In water Ag2O reacted with 48% H2O-soln. of HBF4;
boron trioxide

boron trioxide

sulfur tetrafluoride
7783-60-0

sulfur tetrafluoride

silver fluoride

silver fluoride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In neat (no solvent) heating a mixture of AgF and B2O3 (molar ratio 2 : 1) with an excess of SF4 in a closed steel tube at 175°C;;
boron trioxide

boron trioxide

silver fluoride

silver fluoride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In neat (no solvent) heating at 175°C;;
In neat (no solvent) heating at 175°C;;
boron trifluoride
7637-07-2

boron trifluoride

silver(I) chloride

silver(I) chloride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cl2; evaporation of an excess of BF3;;
boron trifluoride
7637-07-2

boron trifluoride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
With Ag borate
With Ag borate
hydrogen fluoride
7664-39-3

hydrogen fluoride

boron trifluoride
7637-07-2

boron trifluoride

silver
7440-22-4

silver

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In nitromethane addition of powdered Ag to a solution of HF and BF3 in CH3NO2;;
boron trifluoride
7637-07-2

boron trifluoride

silver fluoride

silver fluoride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In neat (no solvent) evaporation of an excess of BF3;;
In ethylbenzene introduction of gaseous BF3 into a suspension of AgF in ethylbenzene;; not isolated;;
In toluene introduction of gaseous BF3 into a suspension of AgF in toluene and evaporation in vacuum;;
bromine trifluoride
7787-71-5

bromine trifluoride

silver fluoride

silver fluoride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

tetrafluoroboric acid

tetrafluoroboric acid

silver
7440-22-4

silver

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

tetrafluoroboric acid

tetrafluoroboric acid

silver(l) oxide
20667-12-3

silver(l) oxide

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In water 48 % HBF4 was added to Ag2O; MeOH was added, solvent was removed under vac., residue was washed with acetone;
In water23.3 g
ammonium tetrafluroborate
13826-83-0

ammonium tetrafluroborate

silver nitrate

silver nitrate

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In acetonitrile byproducts: NH4NO3; N2 atmosphere; pptn. of NH4NO3; filtn. (removal of pptd. NH4NO3), pptn. on cooling (liq. N2) and solvent evapn., separated salt dried (vac.), recrystd. by addn. of acetone/methanol to the salt soln. in acetonitrile; Ag anal.;92.9 - 96.5
silver fluoride

silver fluoride

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

silver(l) oxide
20667-12-3

silver(l) oxide

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In nitromethane byproducts: AgBO2; addition of 60 g boron fluoride etherate to a suspension of 51.5 g Ag2O in 100 ml CH3NO2 and boiling under stirring for 1.5 hours;; removing CH3NO2 in vacuum; drying in vacuum at 60°C over P2O5 and activated carbon;;
Ag(1+)*BF4(1-)*2C3H6=AgBF4*2C3H6

Ag(1+)*BF4(1-)*2C3H6=AgBF4*2C3H6

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

propene
187737-37-7

propene

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
2Ag(1+)*2BF4(1-)*3C4H6=2AgBF4*3C4H6

2Ag(1+)*2BF4(1-)*3C4H6=2AgBF4*3C4H6

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
In neat (no solvent) at 45°C in 72h;;
uranium pentafluoride
13775-07-0

uranium pentafluoride

AgFBF4

AgFBF4

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

uranium hexafluoride
7783-81-5

uranium hexafluoride

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); room temp.; detd. by IR spectroscopy and X-ray diffraction;
Ag(1+)*BF4(1-)*CH2CHC3H7=AgBF4*CH2CHC3H7
26318-29-6

Ag(1+)*BF4(1-)*CH2CHC3H7=AgBF4*CH2CHC3H7

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

Ag(1+)*BF4(1-)*2CH2CHC3H7=AgBF4*2CH2CHC3H7

Ag(1+)*BF4(1-)*2CH2CHC3H7=AgBF4*2CH2CHC3H7

Conditions
ConditionsYield
In neat (no solvent) decompn. at about -10°C;;
Ag(1+)*BF4(1-)*C6H5C4H4C6H5=AgBF4*C6H5C4H4C6H5
26100-18-5

Ag(1+)*BF4(1-)*C6H5C4H4C6H5=AgBF4*C6H5C4H4C6H5

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In water partial decompn. in H2O;;
Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

A

1-butylene
106-98-9

1-butylene

B

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

(Z)-2-Butene
590-18-1

(Z)-2-Butene

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

Ag(1+)*BF4(1-)*2C4H8=AgBF4*2C4H8

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

trans-2-Butene
624-64-6

trans-2-Butene

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
Ag(1+)*BF4(1-)*3C4H8=AgBF4*3C4H8

Ag(1+)*BF4(1-)*3C4H8=AgBF4*3C4H8

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

(Z)-2-Butene
590-18-1

(Z)-2-Butene

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
Ag(1+)*BF4(1-)*3C4H8=AgBF4*3C4H8

Ag(1+)*BF4(1-)*3C4H8=AgBF4*3C4H8

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
In neat (no solvent) investigation of dissociation;;
In neat (no solvent) investigation of dissociation;;
({(η-C5(CH3)5)2Fe2(CO)2(CS)2}Ag)BF4

({(η-C5(CH3)5)2Fe2(CO)2(CS)2}Ag)BF4

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

{(η-C5(CH3)5)Fe(CO)2(CS)}BF4

{(η-C5(CH3)5)Fe(CO)2(CS)}BF4

Conditions
ConditionsYield
In acetone dissociation on dissoln.;;
In dichloromethane dissociation on dissoln.;;
Ag([Au(μ-C(2),N(3)-1-benzylimidazolato)]3)2BF4*dichloromethane

Ag([Au(μ-C(2),N(3)-1-benzylimidazolato)]3)2BF4*dichloromethane

A

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

B

tris{μ-(1-benzylimidazolato-N(3),C(2))}tri-gold(I)

tris{μ-(1-benzylimidazolato-N(3),C(2))}tri-gold(I)

Conditions
ConditionsYield
In dimethyl sulfoxide decompn.;
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

acetonitrile
75-05-8

acetonitrile

palladium dichloride

palladium dichloride

tetrakis(acetonitrile)palladium(II) tetrafluoroborate
21797-13-7

tetrakis(acetonitrile)palladium(II) tetrafluoroborate

Conditions
ConditionsYield
for 1.5h; Inert atmosphere;100%
In acetonitrile byproducts: AgCl; N2-atmosphere; addn. of PdCl2 to 2 equiv. of AgBF4, stirring (45 min, pptn.); filtration off of AgCl, concn. (vac.), addn. of ether (pptn.), recrystn. (MeCN/ether); elem. anal.;88%
for 2h; Inert atmosphere; Schlenk technique;
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

trans-{RhCl(CO)(DMPM)}2
114445-93-1

trans-{RhCl(CO)(DMPM)}2

{Rh2(CO)2(μ-Cl)(DMPM)2}{BF4}
114446-02-5

{Rh2(CO)2(μ-Cl)(DMPM)2}{BF4}

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; stirring for 40 min; removal of solvent under vac., dissoln. in CH2Cl2, filtn. through Celite, redn. of vol. by a stream of N2, addn. of diethyl ether;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

bis(ethylene)rhodium(I) chloride dimer

bis(ethylene)rhodium(I) chloride dimer

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

di(norbornadiene)rhodium(I) tetrafluoroborate

di(norbornadiene)rhodium(I) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane under N2 or Ar, addn. of diene in CH2Cl2 to Rh-complex in CH2Cl2, then addn. of solid AgBF4, soln. is stirred for 45 min; filtn. through Celite, addn. of THF to the filtrate, concn., filtn. of deep red crystals, washed with THF, air-dried;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

trans-dichlorobis(ethyl diphenylphosphinoacetate)palladium(II)
64492-09-7

trans-dichlorobis(ethyl diphenylphosphinoacetate)palladium(II)

{cis-Pd(Ph2PCH2C(O)OEt)2}(BF4)2
113379-43-4

{cis-Pd(Ph2PCH2C(O)OEt)2}(BF4)2

Conditions
ConditionsYield
In dichloromethane 2 equiv. AgBF4; elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[RuCl2(hexamethylbenzene)]2

[RuCl2(hexamethylbenzene)]2

phenanthrene
85-01-8

phenanthrene

trifluoroacetic acid
76-05-1

trifluoroacetic acid

(η6-hexamethylbenzene)(η6-phenanthrene)ruthenium(II) bis(tetrafluoroborate)

(η6-hexamethylbenzene)(η6-phenanthrene)ruthenium(II) bis(tetrafluoroborate)

Conditions
ConditionsYield
In acetone stirring at room temperature for 30 min, phenanthrene and trifluoroacetic acid were added to the filtrate, boiled under reflux for 2h, cooled; filtered, washed with ether; NMR, UV;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

iron(II) octaethyltetraazaporphyrin
169697-22-7

iron(II) octaethyltetraazaporphyrin

benzyltrimethylammonium chloride
56-93-9

benzyltrimethylammonium chloride

chloroiron(III) 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraazaporphyrinate
141045-99-0

chloroiron(III) 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraazaporphyrinate

Conditions
ConditionsYield
In dichloromethane; toluene byproducts: Ag; inert atmosphere; addn. of AgBF4 to the Fe-complex in toluene; stirred for 30 min; filtration off of Ag (Celite), evapn. (vac.), dissoln. in CH2Cl2, addn. of PhCH2N(CH3)3Cl, stirring (15 min);; filtration (Celite), partial evapn. (vac.), crystn. (hexane/C6H6, slow evapn.);;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

iron(carbonyl)2(trimethylphosphine)2(methyl)I
33542-07-3

iron(carbonyl)2(trimethylphosphine)2(methyl)I

{Fe(CH3)(CO)3(P(CH3)3)2}(1+)*BF4(1-)={Fe(CH3)(CO)3(P(CH3)3)2}BF4

{Fe(CH3)(CO)3(P(CH3)3)2}(1+)*BF4(1-)={Fe(CH3)(CO)3(P(CH3)3)2}BF4

Conditions
ConditionsYield
With carbon monoxide In dichloromethane; acetone under argon; stirred for 13 h at room temp.;; filtn.; dried;;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[(((CH3)3C)3P)2Au](1+)*Cl(1-)=[(((CH3)3C)3P)2Au]Cl
159161-46-3

[(((CH3)3C)3P)2Au](1+)*Cl(1-)=[(((CH3)3C)3P)2Au]Cl

bis(tri-t-butylphosphine)gold(I) tetrafluoroborate
168000-65-5

bis(tri-t-butylphosphine)gold(I) tetrafluoroborate

Conditions
ConditionsYield
In ethanol byproducts: AgCl; N2 atm., protection agains light; 1 equiv. of AgBF4, room temp., stirring (30 min); filtn., evapn. (vac.), crystn. (CH2Cl2/Et2O, -30°C), drying (vac.); elem. anal.;100%
dichloro(benzene)ruthenium(II) dimer
37366-09-9

dichloro(benzene)ruthenium(II) dimer

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

<23>(1,3,5)-cyclophane
27165-88-4

<23>(1,3,5)-cyclophane

(η6-benzene)(η6-[2(3)](1,3,5)cyclophane)ruthenium(II) bis(tetrafluoroborate)
101810-15-5

(η6-benzene)(η6-[2(3)](1,3,5)cyclophane)ruthenium(II) bis(tetrafluoroborate)

Conditions
ConditionsYield
In acetone; trifluoroacetic acid byproducts: AgCl; a soln. of Ru2-compd. and AgBF4 in acetone was stirred at room temp. for 30 min; after removing AgCl by filtration (2(3))(1,3,5)cyclophane and CF3CO2H were added; the mixt. was boiled under reflux for 1 h; the mixt. was cooled to 0°C and dild. with ether; the ppt. was collected by filtration and washed with ether, then dissolved in CH3NO2 and reprecipitated by addn. of ether; elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

fac-IrH3(PMe2Ph)3
12099-83-1, 92621-06-2

fac-IrH3(PMe2Ph)3

[(fac-IrH3(PMe2Ph)3)2Ag]BF4

[(fac-IrH3(PMe2Ph)3)2Ag]BF4

Conditions
ConditionsYield
In tetrahydrofuran100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[Pt(8-methylquinolinyl)Me2(2,2'-bipyridine)]Br

[Pt(8-methylquinolinyl)Me2(2,2'-bipyridine)]Br

[Pt(8-methylquinolinyl)Me2(2,2'-bipyridine)]BF4

[Pt(8-methylquinolinyl)Me2(2,2'-bipyridine)]BF4

Conditions
ConditionsYield
In acetone byproducts: AgBr; addn. of stoich. amt. of AgBF4 to metal complex, stirring for 5 min; filtartion off of AgBr (Celite), vol. reduction, Et2O addn., cooling to -30°C overnight, collection (filtration), drying (vac.); elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[Pd(Me)(1,3-dimethylimidazolin-2-ylidene)(μ-Cl)]2

[Pd(Me)(1,3-dimethylimidazolin-2-ylidene)(μ-Cl)]2

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

[Pd(Me)(1,3-dimethylimidazol-2-ylidene)(1,5-cyclooctadiene)]BF4

[Pd(Me)(1,3-dimethylimidazol-2-ylidene)(1,5-cyclooctadiene)]BF4

Conditions
ConditionsYield
In dichloromethane byproducts: AgCl; absence of air and moisture; addn. of 1 equiv. COD to Pd-complex soln. at -15°C, stirring for 10 min, addn. of equimolar amt. of AgBF4 soln. at -20°C, stirring (-20°C, 1 h); filtration (Celite), solvent removal (vac., -15 to -20°C); elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

1,1′,2,2′-tetrakis(diphenylphosphino)-4,4′-di-tert-butylferrocene
403815-19-0

1,1′,2,2′-tetrakis(diphenylphosphino)-4,4′-di-tert-butylferrocene

Fe(C5H2C(CH3)3(P(C6H5)2)2)2Rh(CO)2(1+)*BF4(1-)=Fe(C5H2C(CH3)3(P(C6H5)2)2)2Rh(CO)2BF4
403815-23-6

Fe(C5H2C(CH3)3(P(C6H5)2)2)2Rh(CO)2(1+)*BF4(1-)=Fe(C5H2C(CH3)3(P(C6H5)2)2)2Rh(CO)2BF4

Conditions
ConditionsYield
In methanol; toluene (Ar); addn. of a soln. of silver salt in methanol to a soln. of iron complex in toluene, addn. of a soln. of rhodium complex in toluene, stirring for 30 min; filtration, evapn.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

5-(4-pyridyl)-10,15,20-triphenylporphyrin

5-(4-pyridyl)-10,15,20-triphenylporphyrin

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]
178438-03-4

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]

((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))2C6H3(CH2OC6H2(CH2SC6H5)2Pd)2CH2CN(2+)*2BF4(1-)=[C136H99N11O2Pd2S4][BF4]2

((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))2C6H3(CH2OC6H2(CH2SC6H5)2Pd)2CH2CN(2+)*2BF4(1-)=[C136H99N11O2Pd2S4][BF4]2

Conditions
ConditionsYield
In nitromethane; dichloromethane; water stirring (5 min); solvent removal (vac.), dissolving in MeNO2 and evpn. to dryness (repeated twice), dissolving (MeNO2), filtn.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[(PdCl(C6H5SCH2)2C6H2OCH2)3C6H3]
178438-02-3

[(PdCl(C6H5SCH2)2C6H2OCH2)3C6H3]

((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))2C6H3(CH2OC6H2(CH2SC6H5)2Pd)2CH2CN(2+)*2BF4(1-)=[C136H99N11O2Pd2S4][BF4]2

((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))2C6H3(CH2OC6H2(CH2SC6H5)2Pd)2CH2CN(2+)*2BF4(1-)=[C136H99N11O2Pd2S4][BF4]2

C69H57O3Pd3S6(3+)*3C50H41NO2Pd2S4(2+)*6C43H29N5*9BF4(1-) = [(C69H57O3Pd3S6)(C50H41NO2Pd2S4)3(C43H29N5)6][BF4]9

C69H57O3Pd3S6(3+)*3C50H41NO2Pd2S4(2+)*6C43H29N5*9BF4(1-) = [(C69H57O3Pd3S6)(C50H41NO2Pd2S4)3(C43H29N5)6][BF4]9

Conditions
ConditionsYield
In nitromethane; dichloromethane; water stirring (5 min); solvent removal (vac.), dissolving in MeNO2 and evpn. to dryness (repeated twice), dissolving (MeNO2), filtn.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

5-(4-pyridyl)-10,15,20-triphenylporphyrin

5-(4-pyridyl)-10,15,20-triphenylporphyrin

[(PdCl(C6H5SCH2)2C6H2OCH2)3C6H3]
178438-02-3

[(PdCl(C6H5SCH2)2C6H2OCH2)3C6H3]

3((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))*C6H3(CH2OC6H2(CH2SC6H5)2Pd)3(3+)*3BF4(1-)=[(C43H29N5)3(C69H57O3Pd3S6)][BF4]3

3((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))*C6H3(CH2OC6H2(CH2SC6H5)2Pd)3(3+)*3BF4(1-)=[(C43H29N5)3(C69H57O3Pd3S6)][BF4]3

Conditions
ConditionsYield
In nitromethane; dichloromethane; water stirring (5 min); solvent removal (vac.), dissolving in MeNO2 and evpn. to dryness (repeated twice), dissolving (MeNO2), filtn.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))2C6H3(CH2OC6H2(CH2SC6H5)2Pd)2CH2CN(2+)*2BF4(1-)=[C136H99N11O2Pd2S4][BF4]2

((C4H2NHCC6H5)2(C4H2NCC6H5)(C4H2NCC5H4N))2C6H3(CH2OC6H2(CH2SC6H5)2Pd)2CH2CN(2+)*2BF4(1-)=[C136H99N11O2Pd2S4][BF4]2

C69H57O3Pd3S6(3+)*3C50H41NO2Cl2Pd2S4*3BF4(1-) = [(C69H57O3Pd3S6)(C50H41NO2Cl2Pd2S4)3][BF4]3

C69H57O3Pd3S6(3+)*3C50H41NO2Cl2Pd2S4*3BF4(1-) = [(C69H57O3Pd3S6)(C50H41NO2Cl2Pd2S4)3][BF4]3

C69H57O3Pd3S6(3+)*9C50H41NO2Pd2S4(2+)*12C43H29N5*21BF4(1-) = [(C69H57O3Pd3S6)(C50H41NO2Pd2S4)9(C43H29N5)12][BF4]21

C69H57O3Pd3S6(3+)*9C50H41NO2Pd2S4(2+)*12C43H29N5*21BF4(1-) = [(C69H57O3Pd3S6)(C50H41NO2Pd2S4)9(C43H29N5)12][BF4]21

Conditions
ConditionsYield
In nitromethane; dichloromethane; water stirring (5 min); solvent removal (vac.), dissolving in MeNO2 and evpn. to dryness (repeated twice), dissolving (MeNO2), filtn.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]
178438-03-4

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]

[(PdCl(C6H5SCH2)2C6H2OCH2)3C6H3]
178438-02-3

[(PdCl(C6H5SCH2)2C6H2OCH2)3C6H3]

9Pd(2+)*C69H57O3S6(3-)*3C50H41NO2S4(2-)*6Cl(1-)*3BF4(1-)*CH3NO2=C219H180B3N3O9F12S18Cl6Pd9*CH3NO2

9Pd(2+)*C69H57O3S6(3-)*3C50H41NO2S4(2-)*6Cl(1-)*3BF4(1-)*CH3NO2=C219H180B3N3O9F12S18Cl6Pd9*CH3NO2

Conditions
ConditionsYield
In nitromethane; dichloromethane byproducts: AgCl; 3 equiv. of AgBF4, 3 equiv. of R-CN block, stirring (ratio CH2Cl2/CH3NO21/1); filtration (over hyflo), chromatography (SiO2, CH3NO2);100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]
178438-03-4

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]

9Pd(2+)*C69H57O3S6(3-)*3C50H41NO2S4(2-)*6Cl(1-)*3BF4(1-)*CH3NO2=C219H180B3N3O9F12S18Cl6Pd9*CH3NO2

9Pd(2+)*C69H57O3S6(3-)*3C50H41NO2S4(2-)*6Cl(1-)*3BF4(1-)*CH3NO2=C219H180B3N3O9F12S18Cl6Pd9*CH3NO2

21Pd(2+)*C69H57O3S6(3-)*9C50H41NO2S4(2-)*12Cl(1-)*9BF4(1-)*2CH3NO2=C519H426B9N9O21F36S42Cl12Pd21*2CH3NO2

21Pd(2+)*C69H57O3S6(3-)*9C50H41NO2S4(2-)*12Cl(1-)*9BF4(1-)*2CH3NO2=C519H426B9N9O21F36S42Cl12Pd21*2CH3NO2

Conditions
ConditionsYield
In nitromethane; dichloromethane byproducts: AgCl; 3 equiv. of AgBF4, 3 equiv. of R-CN block, stirring (ratio CH2Cl2/CH3NO21/1); filtration (over hyflo), chromatography (SiO2, CH3NO2);100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]
178438-03-4

[(PdCl(C6H5SCH2)2C6H2OCH2)2C6H3CH2CN]

21Pd(2+)*C69H57O3S6(3-)*9C50H41NO2S4(2-)*12Cl(1-)*9BF4(1-)*2CH3NO2=C519H426B9N9O21F36S42Cl12Pd21*2CH3NO2

21Pd(2+)*C69H57O3S6(3-)*9C50H41NO2S4(2-)*12Cl(1-)*9BF4(1-)*2CH3NO2=C519H426B9N9O21F36S42Cl12Pd21*2CH3NO2

45Pd(2+)*C69H57O3S6(3-)*21C50H41NO2S4(2-)*24Cl(1-)*21BF4(1-)*10CH3NO2=C1119H918B21N21O45F84S90Cl24Pd45*10CH3NO2

45Pd(2+)*C69H57O3S6(3-)*21C50H41NO2S4(2-)*24Cl(1-)*21BF4(1-)*10CH3NO2=C1119H918B21N21O45F84S90Cl24Pd45*10CH3NO2

Conditions
ConditionsYield
In nitromethane; dichloromethane byproducts: AgCl; 3 equiv. of AgBF4, 3 equiv. of R-CN block, stirring (ratio CH2Cl2/CH3NO21/1); filtration (over hyflo), chromatography (SiO2, CH3NO2);100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

di-μ-chloro-bis[η**3-2-butenyl]dipalladium

di-μ-chloro-bis[η**3-2-butenyl]dipalladium

[η**3-2-butenyl](N,N,N',N'-tetramethylethylenediamine)palladium(II) tetrafluoroborate

[η**3-2-butenyl](N,N,N',N'-tetramethylethylenediamine)palladium(II) tetrafluoroborate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; π-2-butenylpalladium chloride dimer dissolved in THF; AgBF4 added; stirred 10 min; AgCl removed and washed with THF; TMEDA added dropwise toTHF extracts, stirred 10 min; solvent vac. removed; elem. anal.;100%
pyridine
110-86-1

pyridine

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

Pd(C5H3N(CH2P(C6H5)2)2)Cl2
331861-55-3, 104578-19-0

Pd(C5H3N(CH2P(C6H5)2)2)Cl2

Pd(C5H3N(CH2P(C6H5)2)2)(C5H5N)(2+)*2BF4(1-)=[Pd(C5H3N(CH2P(C6H5)2)2)(C5H5N)](BF4)2

Pd(C5H3N(CH2P(C6H5)2)2)(C5H5N)(2+)*2BF4(1-)=[Pd(C5H3N(CH2P(C6H5)2)2)(C5H5N)](BF4)2

Conditions
ConditionsYield
In dichloromethane byproducts: AgCl; Ar-atmosphere; filtering, concg., crystn. on Et2O addn. (2 - 3 h, -20°C), filtering, washing (Et2O), drying (vac.); elem. anal.;100%
5,17-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene
655244-42-1

5,17-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

poly[(5,17-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene) silver(I)] tetrafluoroborate
655244-44-3

poly[(5,17-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene) silver(I)] tetrafluoroborate

Conditions
ConditionsYield
In acetonitrile soln. calix(4)arene in MeCN was added to soln. AgBF4 in MeCN and stirredfor 1 h at room temp.; solvent was evapd.; elem. anal.;100%
5,11-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene
655244-36-3

5,11-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene

silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

poly[(5,11-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene) silver(I)] tetrafluoroborate
655244-38-5

poly[(5,11-diisocyanato-25,26,27,28-tetrapropoxycalix[4]arene) silver(I)] tetrafluoroborate

Conditions
ConditionsYield
In acetonitrile soln. calix(4)arene in MeCN was added to soln. AgBF4 in MeCN and stirredfor 1 h at room temp.; solvent was evapd.; elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[Cu(C12H6N2)4(C6H4)6(OCH2CH2)12O2](1+)*BF4(1-)=[Cu(C12H6N2)4(C6H4)6(OCH2CH2)12O2][BF4]
178690-91-0

[Cu(C12H6N2)4(C6H4)6(OCH2CH2)12O2](1+)*BF4(1-)=[Cu(C12H6N2)4(C6H4)6(OCH2CH2)12O2][BF4]

[CuAg(C12H6N2)4(C6H4)6(OCH2CH2)12O2](2+)*2BF4(1-)=[CuAg(C12H6N2)4(C6H4)6(OCH2CH2)12O2][BF4]2

[CuAg(C12H6N2)4(C6H4)6(OCH2CH2)12O2](2+)*2BF4(1-)=[CuAg(C12H6N2)4(C6H4)6(OCH2CH2)12O2][BF4]2

Conditions
ConditionsYield
In dichloromethane; benzene excess of AgBF4, stirring (room temp., overnight); pptn., addn. of H2O, decantation, washing (H2O), drying (MgSO4), crystn.(C6H6/CH2Cl2);100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

1,5-dithia-7-cyclononyne
153615-59-9

1,5-dithia-7-cyclononyne

Ag(1+)*C7H10S2*BF4(1-) = [Ag(C7H10S2)]BF4
188485-85-0

Ag(1+)*C7H10S2*BF4(1-) = [Ag(C7H10S2)]BF4

Conditions
ConditionsYield
In tetrahydrofuran (N2); elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

1,6-dithiacyclodec-8-yne
180135-36-8

1,6-dithiacyclodec-8-yne

Ag(1+)*C8H12S2*BF4(1-) = [Ag(C8H12S2)]BF4
188485-89-4

Ag(1+)*C8H12S2*BF4(1-) = [Ag(C8H12S2)]BF4

Conditions
ConditionsYield
In tetrahydrofuran (N2); elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

1,5-dithiacyclonon-7-yne-3-ol
180135-35-7

1,5-dithiacyclonon-7-yne-3-ol

Ag(1+)*C7H10OS2*BF4(1-) = [Ag(C7H10OS2)]BF4
188485-97-4

Ag(1+)*C7H10OS2*BF4(1-) = [Ag(C7H10OS2)]BF4

Conditions
ConditionsYield
In tetrahydrofuran (N2); elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

1,7-dithia-4-oxa-cycloundec-9-yne
153615-60-2

1,7-dithia-4-oxa-cycloundec-9-yne

Ag(1+)*C8H12OS2*BF4(1-) = [Ag(C8H12OS2)]BF4
188486-01-3

Ag(1+)*C8H12OS2*BF4(1-) = [Ag(C8H12OS2)]BF4

Conditions
ConditionsYield
In tetrahydrofuran (N2); elem. anal.;100%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

1,4,9,12-tetrathiacyclohexadec-6,14-diyne
180135-32-4

1,4,9,12-tetrathiacyclohexadec-6,14-diyne

2Ag(1+)*C12H16S4*2BF4(1-) = [Ag2(C12H16S4)](BF4)2

2Ag(1+)*C12H16S4*2BF4(1-) = [Ag2(C12H16S4)](BF4)2

Conditions
ConditionsYield
In tetrahydrofuran (N2); elem. anal.;100%

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