1015085-05-8

Basic information

• Product Name: 1-(2-methoxyphenyl)-2-(triphenyl-λ⁵-phosphaneylidene)ethan-1-one
• Synonyms: 1-(2-methoxyphenyl)-2-(triphenyl-λ⁵-phosphaneylidene)ethan-1-one
• CAS NO: 1015085-05-8
• Molecular Weight: 410.452
• Mol File: 1015085-05-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-(2-methoxyphenyl)-2-(triphenyl-λ⁵-phosphaneylidene)ethan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-methoxyphenyl)-2-(triphenyl-λ⁵-phosphaneylidene)ethan-1-one(1015085-05-8)
• EPA Substance Registry System: 1-(2-methoxyphenyl)-2-(triphenyl-λ⁵-phosphaneylidene)ethan-1-one(1015085-05-8)

Safety Data

• Hazardous Substances Data: 1015085-05-8(Hazardous Substances Data)

Upstream product

• 31949-21-0 bromomethyl 2-methoxyphenyl ketone 
• 603-35-0 triphenylphosphine 
• 118-93-4 o-hydroxyacetophenone 
• 579-74-8 2-Methoxyacetophenone 
• 82320-69-2 (2-methoxybenzoylmethyl)triphenylphosphonium bromide 

Downstream Products

• 1015085-06-9 [NiPh(Ph₂PCHC(O)(o-OMeC₆H₄))(PPh₃)] 
• 1256284-95-3 1-(2-methoxyphenyl)-2-(9-methyl-2,3,4,9-tetrahydro-1H-carbazol-4-yl)ethanone 
• 77942-10-0 1-(2-methoxyphenyl)prop-2-en-1-one 
• 1309371-20-7 (E)-1-(2-methoxyphenyl)-3-(2-nitrophenyl)prop-2-en-1-one 

Relevant articles and documents

Copper-Catalyzed N-O Cleavage of α,β-Unsaturated Ketoxime Acetates toward Structurally Diverse Pyridines

The copper-catalyzed [4 + 2] annulation of α,β-unsaturated ketoxime acetates with 1,3-dicarbonyl compounds for the synthesis of three classes of structurally diverse pyridines has been developed. This method employs 1,3-dicarbonyl compounds as C2 synthons and enables the synthesis of multifunctionalized pyridines with diverse electron-withdrawing groups in moderate to good yields. The mechanistic investigation suggests that the reactions proceed through an ionic pathway.

Organocatalytic Enantioselective Selenosulfonylation of a C-C Double Bond to Form Two Stereogenic Centers in an Aqueous Medium

Organocatalytic selenosulfonylation of the C-C double bond of α,β-unsaturated ketones to construct two contiguous stereogenic centers in an aqueous medium was described. A series of α-selenyl and β-sulfonyl ketones with various functional groups were synthesized in good yields and enantioselectivities with saturated NaCl solution as the solvent. In addition, this protocol had been successfully scaled up to a decagram scale via a simple workup procedure.

Highly efficient route to functionalized tetrahydrocarbazoles using a tandem cross-metathesis/intramolecular-hydroarylation sequence

The scope of the novel ruthenium-catalyzed tandem cross-metathesis/ intramolecular-hydroarylation sequence is described. This methodology offers a practical and efficient synthesis of structurally diverse and complex tetrahydrocarbazoles in good to excellent yields (up to 98%). Moreover, preliminary efforts towards the development of an enantioselective version of the current process by sequential catalysis with ruthenium complex and chiral amine are presented, with high yields and enantioselectivities (up to 88% yield and 91% ee).