101522-09-2

Basic information

• Product Name: oxo-phenoxy-bis-triethylammonio-phosphorane; dichloride
• Synonyms: oxo-phenoxy-bis-triethylammonio-phosphorane; dichloride
• CAS NO: 101522-09-2
• Molecular Weight: 413.368
• Mol File: 101522-09-2.mol

Chemical Properties

• CAS DataBase Reference: oxo-phenoxy-bis-triethylammonio-phosphorane; dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: oxo-phenoxy-bis-triethylammonio-phosphorane; dichloride(101522-09-2)
• EPA Substance Registry System: oxo-phenoxy-bis-triethylammonio-phosphorane; dichloride(101522-09-2)

Safety Data

• Hazardous Substances Data: 101522-09-2(Hazardous Substances Data)

Upstream product

• 770-12-7 O-phenyl phosphorodichloridate 
• 121-44-8 triethylamine 

Relevant articles and documents

New phosphorus- and nitrogen-containing poly(methyl methacrylate)-based copolymer: Enhanced flame retardancy and thermal stability

Pure poly(methyl methacrylate) (PMMA) always exhibits high flammability and low thermal stability. To address that, a novel reactive comonomer containing phosphorus and nitrogen elements, 4-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl) phenyl diethylphosphoramidate (PDM), was successfully synthesized and then introduced into PMMA matrix through emulsion copolymerization method. The structure of PDM and as-obtained poly(MMA-co-PDM) copolymers was characterized using Fourier transform infrared (FT-IR), 1H nuclear magnetic resonance spectroscopy (1H NMR) and 31P NMR. From thermal gravimetric analysis and microscale combustion calorimeter, the poly(MMA-co-PDM) copolymers exhibit significantly enhanced flame retardancy and thermal stability, such as the higher degradation temperatures, and decreased peak heat release rate (maximally by 24.1%) and total heat release (maximally by 22.1%). The glass transition temperature (Tg) values of poly(MMA-co-PDM) copolymers obtained by differential scanning calorimetry slightly decrease as the raising flexibility of polymer chain. The char residue analysis by scanning electron microscopy and FT-IR demonstrates that the incorporation of PDM can catalyze the charring of copolymers in condensed phase and form an excellent thermal stability char residue with aromatic structure, further preventing the inner substrate from further combustion. The detailed mechanism was proposed.

Synthesis of a novel highly effective flame retardant containing multivalent phosphorus and its application in unsaturated polyester resins

Unsaturated polyester resin (UP) as one of the most important thermoset materials often exhibits serious fire hazards. Conventional phosphorus-containing reactive flame ratardants could overcome the deficiency of additive flame retardants in UP, but they