10154-05-9

Basic information

• Product Name: 4,8,12-Tetradecatrienoic acid, 5,9,13-trimethyl-, methyl ester, (4E,8E)-
• Synonyms: 4,8,12-Tetradecatrienoic acid, 5,9,13-trimethyl-, methyl ester, (4E,8E)-
• CAS NO: 10154-05-9
• Molecular Formula: C18H30 O2
• Molecular Weight: 278.43
• Mol File: 10154-05-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4,8,12-Tetradecatrienoic acid, 5,9,13-trimethyl-, methyl ester, (4E,8E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4,8,12-Tetradecatrienoic acid, 5,9,13-trimethyl-, methyl ester, (4E,8E)-(10154-05-9)
• EPA Substance Registry System: 4,8,12-Tetradecatrienoic acid, 5,9,13-trimethyl-, methyl ester, (4E,8E)-(10154-05-9)

Safety Data

• Hazardous Substances Data: 10154-05-9(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 6040-06-8 (4E,8E,12E)-5,9,13-trimethyl-4,8,12-tetradecatrienoic acid 
• 67-56-1 methanol 
• 111074-87-4 (6E,10E)-methyl 7,11,15-trimethyl-3-oxohexadeca-6,10,14-trienoate 
• 79491-08-0 dimethyl 2-(3,7,11-trimethyldodeca-2,6,10-trienyl)malonate 
• 1117-52-8 6,10,14-trimethyl-5,9,13-pentadecatriene-2-on 
• 24163-93-7 farnesyl bromide 
• 488115-81-7 (2E/Z,6E)-farnesyl bromide 
• 106-28-5 Farnesol 
• 111074-88-5 (6E,10E)-methyl 2,7,11,15-tetramethyl-3-oxohexadeca-6,10,14-trienoate 
• 58456-69-2 Ethyl 2-carbethoxy-5,9,13-trimethyltetradeca-4(E),8(E),12-trienoate 

Downstream Products

• 79491-08-0 dimethyl 2-(3,7,11-trimethyldodeca-2,6,10-trienyl)malonate 
• 203985-85-7 (4R,2'S,5'E,9'E)-3-(1'-Oxo-2'-prop-2''-enyl-6',10',14'-trimethylpentadeca-5',9',13'-trienyl)-4-benzyloxazolidin-2-one 
• 203985-84-6 (4R,5'E,9'E)-3-(1'-Oxo-6',10',14'-trimethylpentadeca-5',9',13'-trienyl)-4-benzyloxazolidin-2-one 
• 197590-02-6 (4S,2'R,5'E,9'E)-3-(1'-Oxo-2'-prop-2''-enyl-6',10',14'-trimethylpentadeca-5',9',13'-trienyl)-4-benzyloxazolidin-2-one 
• 197590-01-5 (4S,5'E,9'E)-3-(1'-Oxo-6',10',14'-trimethylpentadeca-5',9',13'-trienyl)-4-benzyloxazolidin-2-one 

Relevant articles and documents

SUPERACID CYCLIZATION OF ESTERS OF SOME BISHOMOISOPRENOID ACIDS

It is shown that on the superacid cyclization of esters of bishomobicyclogeranylgeranic and E,E-bishomofarnesic acids fully cyclized hydroxyesters are formed in good yield, while on the interaction of esters of 6-hydroxy- and 6-acyloxy-15-bishomobicyclogeranylgeranic acids with a superacid no carbocyclization takes place.

Stereoselective syntheses of (+)-rhopaloic acid A and (-)-ent- and (±)-rac-rhopaloic acid A

Rhopaloic acid A (+)-1 and the related compounds (-)-ent-1 and (±)-rac-1 have been stereoselectively synthesized. The synthetic strategy consists of successive homologation of (2E,6E)-farnesol 7 and cyclization to form a tetrahydropyran ring, together wit

Stereochemical Studies on Porphyrin a: Assignment of the Absolute Configuration of a Model Porphyrin by Degradation

The synthesis is described of a porphyrin alcohol (22) which has a structure very similar to that of porphyrin a (2).The model porphyrin was resolved by separation of its camphanate esters.Ozonolysis of the 2-nitrobenzoate of each enantiomer in tritiated form gave a derivative of 2-hydroxypentadioic acid whose configuration was determined by dilution analysis.It is demonstrated that correlation of the stereochemistry of porphyrin a with that of the model (22) will be possible by means of the (1)H and (19)F n.m.r. spectra of the corresponding esters with (-)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoic acid.