101577-33-7

Usage

InChI:InChI=1/C17H24O3/c1-5-20-16(19)8-6-7-15(18)13-9-11-14(12-10-13)17(2,3)4/h9-12H,5-8H2,1-4H3

Upstream product

• 140-88-5 ethyl acrylate 
• 70356-09-1 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione 
• 5205-39-0 ethyl glutaroyl chloride 

Downstream Products

• 101100-63-4 5-(4-tertbutylphenyl)-4-hydroxypentanoic 
• 102003-61-2 5-[4-(tert.butyl)phenyl]pentanoyl chloride 
• 97692-66-5 5-(4-tert-butyl-phenyl)-5-oxo-valeric acid 

Relevant academic research and scientific papers

Sequential Michael addition/retro-Claisen condensation of aromatic β-diketones with α,β-unsaturated esters: An approach to obtain 1,5-ketoesters

A K2CO3-catalyzed one-pot protocol involving sequential C-C bond formation and cleavage of aromatic β-diketones with α,β-unsaturated esters is developed to obtain 1,5-ketoesters. The sequential reaction via Michael addition and retro-Claisen condensation proceeds smoothly under mild conditions in up to 98% isolated yield. The mechanism study disclosed that the cascade process involved C-C bond cleavage of aromatic β-diketone as a phenacyl donor under alcoholic alkalescent conditions.

Inorganic alkali catalytic 1, 5 - ketonic ester apperception compound synthesis method

The invention discloses a synthesis method for a 1,5-ketonic ester compound under catalyzing of inorganic base. The synthesis method comprises the following steps: taking a compound of the general formula I as a raw material, taking inorganic base as a ca