101696-49-5

Upstream product

• 116261-35-9 (3R,5R)-3-(4-Methoxy-benzyloxy)-5-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-tetrahydro-furan-2-ol 
• 33985-40-9 (3aR,4S,6R,6aR)-tetrahydro-6-methoxy-2,2-dimethylfuro-[3,4-d][1,3]dioxole-4-carbaldehyde 
• 99441-05-1 methyl 5,9-anhydro-6,8-dideoxy-2,3-O-(1-methylethylidene)-β-D-allo-non-8-enofuranosid-7-ulose 
• 101696-46-2 (R)-2-((3aR,4R,6R,6aR)-6-Methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-3,4-dihydro-2H-pyran-4-ol 
• 101696-47-3 methyl 5,9-anhydro-6,8-dideoxy-7-O-<(4-methoxyphenyl)methyl>-2,3-O-(1-methylethylidene)-L-glycero-β-D-allo-non-8-enofuranoside 

Downstream Products

• 101696-64-4 methyl (methyl 6-deoxy-2,3-O-(1-methylethylidene)-5-O-(phenylmethyl)-L-glycero-β-D-allo-octofuranosid)uronate 
• 101696-53-1 methyl (methyl 6-deoxy-2,3-O-(1-methylethylidene)-5-O-(phenylmethyl)-L-glycero-β-D-allo-octofuranosid)uronate 7-methanesulfonate 
• 101696-52-0 methyl (methyl 6-deoxy-7-O-<(4-methoxyphenyl)methyl>-2,3-O-(1-methylethylidene)-5-O-(phenylmethyl)-L-glycero-β-D-allo-octofuranosid)uronate 
• 101696-60-0 methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 2,3-diacetate 7-methanesulfonate 
• 55728-21-7 octosyl acid A 
• 101696-51-9 (2R,4R)-4-Benzyloxy-2-(4-methoxy-benzyloxy)-4-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-butyric acid 
• 116185-23-0 methyl 3,7-anhydro-1,6-dideoxy-1-<5-(methoxycarbonyl)-3,4-dihydro-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 
• 101696-58-6 methyl 6-deoxy-5-O-(phenylmethyl)-L-glycero-α-D-allo-octofuranuronate 1,2,3-triacetate 7-methanesulfonate 
• 101696-59-7 methyl 6-deoxy-5-O-(phenylmethyl)-L-glycero-β-D-allo-octofuranuronate 1,2,3-triacetate 7-methanesulfonate 
• 101696-61-1 methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate 
• 101696-50-8 (2R,4R)-4-Hydroxy-2-(4-methoxy-benzyloxy)-4-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-butyric acid 

Relevant academic research and scientific papers

Total synthesis of octosyl acid A. Intramolecular Williamson reaction via a cyclic stannylene derivative

The total synthesis of the title compound has been achieved. The key features involved (i) the construction of a carbon-linked furanoside-pyranoside by a cyclocondensation reaction of compound 8, (ii) the use of the pyran matrix to elaborate the required