101713-95-5

Basic information

• Product Name: 2-Hexanone, 4-hydroxy-5,5-dimethyl-
• CAS NO: 101713-95-5
• Molecular Formula: C8H16O2
• Molecular Weight: 144.214
• Mol File: 101713-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Hexanone, 4-hydroxy-5,5-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 4-hydroxy-5,5-dimethyl-(101713-95-5)
• EPA Substance Registry System: 2-Hexanone, 4-hydroxy-5,5-dimethyl-(101713-95-5)

Safety Data

• Hazardous Substances Data: 101713-95-5(Hazardous Substances Data)

Upstream product

• 630-19-3 pivalaldehyde 
• 93714-15-9 (4R,5S)-2,2,4-Trimethyl-5-phenyl-oxazolidine 

Downstream Products

• 1356447-49-8 (1S,5R)-1-hydroxy-6,6-dimethyl-1-phenyl-5-(triphenylsilyloxy)heptan-3-one 
• 1356447-52-3 (1R,5R)-1-hydroxy-6,6-dimethyl-1-phenyl-5-(triphenylsilyloxy)heptan-3-one 
• 1356447-48-7 (3S,7R)-3-hydroxy-2,2,8,8-tetramethyl-7-(triphenylsilyloxy)nonan-5-one 
• 1356447-51-2 (3R,7R)-3-hydroxy-2,2,8,8-tetramethyl-7-(triphenylsilyloxy)nonan-5-one 
• 1356447-47-6 (3R,7S)-7-hydroxy-2,2,8-trimethyl-3-(triphenylsilyloxy)nonan-5-one 
• 1356447-50-1 (3R,7R)-7-hydroxy-2,2,8-trimethyl-3-(triphenylsilyloxy)nonan-5-one 
• 1356445-88-9 C₃₈H₅₁BO₂Si 
• 1356447-46-5 (+)-(R)-5,5-dimethyl-4-(triphenylsilyloxy)hexan-2-one 
• 1251901-55-9 (+)-(R)-4-(4-methoxybenzyloxy)-5,5-dimethylhexan-2-one 
• 1251901-57-1 (-)-(R)-5,5-dimethyl-4-(trityloxy)hexan-2-one 
• 1251901-56-0 (S)-((R)-2,2-dimethyl-5-oxohexan-3-yl) 3,3,3-trifluoro-2-methoxy-2-phenylpropanoate 

Relevant articles and documents

HIGHLY ENANTIOSELECTIVE ALDOL REACTION OF METHYL KETONES VIA CHIRAL STANNOUS AZAENOLATES

Chiral 1,3-oxazolidines are readily prepared from methyl ketones and chiral norephedrine.Formation of stannous azaenolates from the oxazolidines and reaction with aldehydes followed by removal of the chiral auxiliary lead to the aldol products in high level of enantiomeric putity.