1017295-11-2

Basic information

• Product Name: (R(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl)
• CAS NO: 1017295-11-2
• Molecular Weight: 425.133
• Mol File: 1017295-11-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl)(CAS DataBase Reference)
• NIST Chemistry Reference: (R(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl)(1017295-11-2)
• EPA Substance Registry System: (R(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl)(1017295-11-2)

Safety Data

• Hazardous Substances Data: 1017295-11-2(Hazardous Substances Data)

Upstream product

• 1017295-15-6 (S(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl) 
• 1201-56-5 (1S,2S)-N-Methylpseudoephedrine 
• 1017295-11-2 (R(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl) 
• 14222-20-9 1R,2R-N-methylpseudoephedrine 

Downstream Products

• 1017295-15-6 (S(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl) 
• 1017295-11-2 (R(p))-1,2-ferrocenediyl(BMe(OMe))(SnMe₂Cl) 

Relevant articles and documents

Allylation of ketones with a ferrocene-based planar chiral lewis acid

Flat, like your hand: The heteronuclear bidentate Lewis acid 1,2-Fc(BMeCl)-(SnMe2Cl) is readily resolved into its constituent enantiomers through highly stereoselective complexation with N-methylpseudoephedrine. The resulting planar chiral Lewis acids show optical purities greater than 97 % and, upon conversion to the respective allylborane derivatives (see scheme), rapidly add to ketones with enantiomeric excess of up to 80 %. (Chemical Equation Presented).