101773-24-4

Basic information

• Product Name: 5-allyl-1,2,3-trimethylbenzene
• Synonyms: 5-allyl-1,2,3-trimethylbenzene
• CAS NO: 101773-24-4
• Molecular Weight: 160.259
• Mol File: 101773-24-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 5-allyl-1,2,3-trimethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 5-allyl-1,2,3-trimethylbenzene(101773-24-4)
• EPA Substance Registry System: 5-allyl-1,2,3-trimethylbenzene(101773-24-4)

Safety Data

• Hazardous Substances Data: 101773-24-4(Hazardous Substances Data)

Upstream product

• 5402-60-8 2,6-dimethylbenzyl chloride 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 2551-83-9 allyltrimethoxysilane 
• 24850-33-7 allyltributylstanane 
• 143287-97-2 2,3-dihydro-1H-inden-5-yl trifluoromethanesulfonate 
• 526-73-8 1,2,3-trimethylbenzene 
• 762-72-1 allyl-trimethyl-silane 
• 1470-94-6 5-hydroxy-2,3-dihydro-1H-indene 

Relevant articles and documents

Palladium-Catalyzed Regioselective Allylation of Chloromethyl(hetero)arenes with Allyl Pinacolborate

The palladium-catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para-allylated dearomatization products

Preparation method of allyl aromatic compound

The invention belongs to the technical field of pharmaceutical chemical intermediates, and provides a preparation method of an allyl aromatic compound. The preparation method comprises the following steps: by using benzyl chloride and derivatives thereof as raw materials, reacting with an allyl silane compound in a non-aqueous organic solvent under the effect of metal catalysts and additives, and then converting into the allyl aromatic compound under the effect of protonic acid. The preparation method disclosed by the invention has the advantages of being low in raw material prices, less in reaction step, mild in reaction condition, environmentally friendly, convenient for operation and high in reaction yield.

REACTION OF ALLYLTRIMETHYLSILANE WITH AN AROMATIC COMPOUND USING HYPERVALENT ORGANOIODINE COMPOUND: A NEW ALLYLATION OF AROMATIC COMPOUNDS

New general method for the allylation of aromatic compounds from allyltrimethylsilane utilizing the combination of iodosylbenzene and BF3 OEt2 are described, which is based upon the umpolung of allyltrimethylsilane by way of cationic allylphenyliodonium (III) salt complex as an intermediate.