101773-64-2Relevant articles and documents
Aggregative activation in heterocyclic chemistry. Part 4. Metallation of 2-methoxypyridine: Unusual behaviour of the new unimetal superbase BuLi-Me2N(CH2)2OLi (BuLi-LiDMAE)
Gros, Philippe,Fort, Yves,Caubere, Paul
, p. 3071 - 3080 (1997)
A series of potential unimetal superbases BuLi-ROLi has been studied in order to increase the basicity/ nucleophilicity ratio ([B/N]R) of BuLi. The best [B/N]R ratio is found with BuLi-LiDMAE. This complex base apparently metallates 2-methoxypyridine at t