101823-15-8

Basic information

• Product Name: Benzamide, N-methyl-N-(2-oxopropyl)-
• CAS NO: 101823-15-8
• Molecular Formula: C11H13NO2
• Molecular Weight: 191.23
• Mol File: 101823-15-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzamide, N-methyl-N-(2-oxopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-methyl-N-(2-oxopropyl)-(101823-15-8)
• EPA Substance Registry System: Benzamide, N-methyl-N-(2-oxopropyl)-(101823-15-8)

Safety Data

• Hazardous Substances Data: 101823-15-8(Hazardous Substances Data)

Upstream product

• 65178-52-1 N-allyl-N-methylbenzamide 
• 88070-48-8 N-methylbenzamide 
• 563-47-3 3-Chloro-2-methylpropene 
• 2568-34-5 N-benzoyl-N-methylglycine 
• 108-24-7 acetic anhydride 
• 72552-73-9 N-2-propylidenemethanamide N-oxide 
• 21737-87-1 N-methyl benzimidoyl chloride 

Downstream Products

• 114894-03-0 3-diphenylphosphinoyl-2-methyl-1-(N-methylbenzamido)-propan-2-ol 
• 114894-06-3 N-[(E)-3-(Diphenyl-phosphinoyl)-4-hydroxy-2-methyl-4-phenyl-but-1-enyl]-N-methyl-benzamide 
• 114894-04-1 N-[2-(Diphenyl-phosphinoylmethyl)-allyl]-N-methyl-benzamide 
• 114894-05-2 N-(3-diphenylphosphinoyl-2-methylprop-1-enyl)-N-methyl-benzamide 
• 101823-16-9 Benzoic acid (Z)-2-(benzoyl-methyl-amino)-1-methyl-vinyl ester 

Relevant articles and documents

Catalyst-controlled Wacker-type oxidation of protected allylic amines

On the contrary: Utilizing the [Pd-(quinox)]-TBHP catalyst system, protected allylic amines were oxidized with high selectivity for the methyl ketone product. This is contrary to the results obtained by the substrate-controlled Tsuji-Wacker oxidation, which highlights the catalyst-controlled system presented here (see scheme). A variety of N-pro-tecting groups undergo selective oxidation with high ketone selectivity. TBHP = tert-butylhydroperoxide.

Palladium((II))-catalysed oxidation of carbon-carbon double bonds of allylic compounds with molecular oxygen; Regioselective formation of aldehydes

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AMIDOACETONE ENOLATE ANIONS: ALKYLATION AND MICHAEL REACTION

The lithyum enolate derived from benzamidoacetone (1) can be regiospecifically alkylated at C(1) and stereospecifically added in conjugate fashion to cyclohexenone without resorting to protection of free NH.Comparison is made with alkylations of methyl hippurate.