21737-87-1

Basic information

• Product Name: Benzenecarboximidoyl chloride, N-methyl-
• CAS NO: 21737-87-1
• Molecular Formula: C8H8ClN
• Molecular Weight: 153.611
• Mol File: 21737-87-1.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, N-methyl-(21737-87-1)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, N-methyl-(21737-87-1)

Safety Data

• Hazardous Substances Data: 21737-87-1(Hazardous Substances Data)

Upstream product

• 88070-48-8 N-methylbenzamide 
• 611-74-5 N,N-dimethylbenzamide 
• 2397-26-4 N,N-dimethyl(chlorophenylmethylene)ammonium chloride 
• 65-85-0 benzoic acid 
• 7719-09-7 thionyl chloride 
• 79-16-3 N-methyl-acetamide 
• 21819-41-0 N-benzoyl-N-methylcarbamic acid chloride 

Downstream Products

• 14608-32-3 6-amino-2-phenyl-benzo[e]perimidin-7-one 
• 855339-31-0 N-methyl-N'-(9-oxo-fluoren-1-yl)-benzamidine 
• 1775-61-7 methyl N-methylbenzimidate 
• 65112-55-2 N¹-benzoyl-N¹,N²-dimethylbenzamidine 
• 76894-29-6 N-methyl-benzimidic acid phenyl ester 
• 21864-88-0 N-(α-cyanobenzylidene)methylamine 
• 74030-76-5 2-methyl-3-phenyl-Δ³-1,2,4-thiadiazolin-5-imine hydrochloride 
• 493-77-6 2,4,6-triphenyl-1,3,5-triazine 
• 88070-48-8 N-methylbenzamide 
• 65052-85-9 N-(pyridin-2-yl)-N-methylbenzamide 
• 911125-12-7 N-Methyl-3-cyclopropyl-1-phenylprop-2-yn-1-imine 
• 911125-13-8 C₁₄H₁₇N 
• 1439356-54-3 ethyl 7-fluoro-6-iodo-1-methyl-4-oxo-2-phenyl-1,4-dihydroquinoline-3-carboxylate 
• 1439356-57-6 methyl 7-fluoro-6-iodo-1-methyl-4-oxo-2-phenyl-1,4-dihydroquinoline-3-carboxylate 

Relevant articles and documents

A QSAR for the mutagenic potencies of twelve 2-amino- trimethylimidazopyridine isomers: Structural, quantum chemical, and hydropathic factors

An isomeric series of heterocyclic amines related to one found in heated muscle meats was investigated for properties that predict their measured mutagenic potency. Eleven of the 12 possible 2-amino-trimethylimidazopyridine (TMIP) isomers were tested for

Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis

The metal-free catalytic hydrogenation of secondary carboxylic acid amides is developed. The reduction is realized by two new catalytic reactions. First, the amide is converted into the imidoyl chloride by triphosgene (CO(OCCl3)2) using novel phosphorus(V) catalysts. Second, the in situ generated imidoyl chlorides are hydrogenated in high yields by an FLP-catalyst. Mechanistic and quantum mechanical calculations support an autoinduced catalytic cycle for the hydrogenation with chloride acting as unusual Lewis base for FLP-mediated H2-activation.

Transition metal-free one-pot synthesis of 2-substituted 3-carboxy-4-quinolone and chromone derivatives

A novel one-pot synthesis of the 2-substituted 3-carboxy-4-quinolone/ chromone derivatives from readily available 3-oxo-3-arylpropanoates and amides/acyl chlorides is reported, without any transition metal aid. The Royal Society of Chemistry 2013.

Synthesis of two potential heterocyclic amine food mutagens

(Chemical Equation Presented) The syntheses of two potential food mutagens formed during cooking, 2-amino-3,6,7-trimethyl-3H-imidazo[4,5-b]pyridine (1) and 2-amino-3,6,7-trimethyl-3H-imidazo[4,5-c]pyridine (2), are described.