101855-05-4Relevant academic research and scientific papers
Catalytic conversion of conjugated enones into optically active α-keto aziridines using chiral rare earth metal complexes
Sugihara, Hiroyasu,Daikai, Kazuhiro,Jin, Xiu Lan,Furuno, Hiroshi,Inanaga, Junji
, p. 2735 - 2739 (2007/10/03)
Optically active N-unsubstituted α-keto aziridines 2 were synthesized from conjugated enones 1 via the Sc[(R)-BNP]3-catalyzed enantioselective Michael addition of O-methylhydroxylamine followed by the La(O-i-Pr)3-catalyzed ring closu
