101960-30-9Relevant academic research and scientific papers
Efficient and Flexible Syntheses of Paraconic Esters and Other Highly Substituted Furanone Derivatives from Methyl 2-Siloxycyclopropanecarboxylates
Brueckner, Christiane,Reissig, Hans-Ulrich
, p. 2440 - 2450 (2007/10/02)
Deprotonation of methyl 2-siloxycyclopropanecarboxylates 1 with lithium diisopropylamide and reaction of the resulting enolates with carbonyl compounds produce trifunctional cyclopropane derivatives.These primary adducts can only be isolated with good yie
Synthesis of Functionalized Furan Derivatives by Hydroxyalkylation of Methyl 2-Siloxycyclopropanecarboxylates
Brueckner, Christiane,Reissig, Hans-Ulrich
, p. 1512 - 1513 (2007/10/02)
A variety of methyl tetrahydrofuran-3-carboxylates (4) or the 5-oxo analogues (6) are available in good overall yield by deprotonation of cyclopropanes (1), addition of carbonyl compounds, ring cleavage, and reductive or oxidative work-up, respectively.
