101981-06-0Relevant articles and documents
The Influence of a Substituent with Free Radical Character (Reverse Effect) on Some Nucleophilic Substitutions involving Benzylic Systems
Ballester, Manuel,Veciana, Jaime,Riera, Juan,Castaner, Juan,Armet, Olga,Rovira, Concepcion
, p. 982 - 983 (1983)
The free radical character of the benzyl bromide (1) causes accelerations in the nucleophilic substitution reactions with acetate and with diethyl malonate anions which are interpreted in terms of a change-transfer, biradical configuration for the SN2 transition state.