1020068-81-8

Basic information

• Product Name: (1R,2S,7R,8R,9R)-9-benzyloxy-6-isopropyl-9,13-dimethyl-15-oxa-tricyclo[6.6.1(1,8).0(2,7)]pentadec-12-en-3-one
• Synonyms: (1R,2S,7R,8R,9R)-9-benzyloxy-6-isopropyl-9,13-dimethyl-15-oxa-tricyclo[6.6.1(1,8).0(2,7)]pentadec-12-en-3-one
• CAS NO: 1020068-81-8
• Molecular Weight: 396.57
• Mol File: 1020068-81-8.mol

Chemical Properties

• CAS DataBase Reference: (1R,2S,7R,8R,9R)-9-benzyloxy-6-isopropyl-9,13-dimethyl-15-oxa-tricyclo[6.6.1(1,8).0(2,7)]pentadec-12-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,7R,8R,9R)-9-benzyloxy-6-isopropyl-9,13-dimethyl-15-oxa-tricyclo[6.6.1(1,8).0(2,7)]pentadec-12-en-3-one(1020068-81-8)
• EPA Substance Registry System: (1R,2S,7R,8R,9R)-9-benzyloxy-6-isopropyl-9,13-dimethyl-15-oxa-tricyclo[6.6.1(1,8).0(2,7)]pentadec-12-en-3-one(1020068-81-8)

Safety Data

• Hazardous Substances Data: 1020068-81-8(Hazardous Substances Data)

Upstream product

• 1020068-79-4 [1R,3R,3aS,7R,7aR,1(1R)]-1-(2-benzyloxyhex-5-en-2-yl)-7-isopropyl-3-(2-methylallyl)-hexahydroisobenzofuran-4(1H)-one 

Downstream Products

• 1020068-86-3 (1S,2R,4R,6S,9R,10R,11R)-9-benzyloxy-12-isopropyl-4,9-dimethyl-5,16-dioxa-tetracyclo[9.4.1(2,10).0(4,6).0(1,11)]hexadeca-15-one 
• 1020068-84-1 (1S,2R,4S,6R,9R,10R,11R)-9-benzyloxy-12-isopropyl-4,9-dimethyl-5,16-dioxa-tetracyclo[9.4.1(2,10).0(4,6).0(1,11)]hexadeca-15-one 

Relevant articles and documents

Asymmetric total synthesis and X-ray crystal structure of the cytotoxic marine diterpene (+)-vigulariol

(Figure Presented) A crystal from the China sea: The asymmetric total synthesis of (+)-vigulariol (see picture: red O, blue C, white H) has been accomplished in eight linear steps starting from (R)-cryptone, which is readily available from eucalyptus oil. Key steps involve an asymmetric homoaldol reaction of chiral allyl carbamates and THF cyclocondensation. Ring-closing metathesis led to the tricyclic framework of the cladiellin diterpenes.