1020166-25-9Relevant academic research and scientific papers
Pyrimidines as Surrogates for 1,3-Dicarbonyl Compounds in peri Annulation of Perimidines en Route to 1,3-Diazapyrenes
Aksenov, Alexander V.,Shcherbakov, Stanisvlav V.,Lobach, Irina V.,Aksenova, Inna V.,Rubin, Michael
, p. 1666 - 1673 (2017)
A highly efficient protocol for acid-mediated peri annulation of perimidines with pyrimidines has been developed. Pyrimidines, used as surrogates for 1,3-dicarbonyl compounds, furnish benzo[gh]perimidines, which includes hardly available analogues, non-substituted, or mono-substituted at C-6, C-8. Limitations of reactions that use 5-bromopyrimidines are investigated.
Novel approach to the synthesis of 1,3-diazapyrenes
Aksenov,Borovlev,Aksenova,Lobach,Lyakhovnenko
, p. 66 - 69 (2009)
Methods have been developed for the synthesis of 1,3-diazapyrenes based on the reactions of perimidines with ethoxymethylene-1,3-dicarbonyl compounds and also 6(7)-benzoyl(acetyl, formyl)perimidines with carbonyl compounds in PPA.
