1020169-08-7Relevant academic research and scientific papers
Reactivity of mononuclear alkylperoxo copper(II) complex. O-O bond cleavage and C-H bond activation
Kunishita, Atsushi,Ishimaru, Hirohito,Nakashima, Satoru,Ogura, Takashi,Itoh, Shinobu
, p. 4244 - 4245 (2008)
A detailed reactivity study has been carried out for the first time on a new mononuclear alkylperoxo copper(II) complex, which is generated by the reaction of copper(II) complex supported by the bis(pyridylmethyl)amine tridentate ligand containing a phenyl group at the 6-position of the pyridine donor groups and cumene hydroperoxide (CmOOH) in CH3CN. The cumylperoxo copper(II) complex thus obtained has been found to undergo homolytic cleavage of the O-O bond and induce C-H bond activation of exogenous substrates, providing important insights into the catalytic mechanism of copper monooxygenases. Copyright
