102058-66-2

Upstream product

• 102058-65-1 5,9-Dimethyl-1-hydroxy-Δ⁵-octalon-6 
• 98-88-4 benzoyl chloride 
• 24138-10-1 (+/-)-(4aβ,5β)-4,4a,5,6,7,8-hexahydro-5-hydroxy-1,4a-dimethylnaphthalen-2(3H)-one 
• 41019-71-0 (+/-)-3,4,8,8a-tetrahydro-5,8a-dimethyl-1,6(2H,7H)-naphthalenedione 

Downstream Products

• 102058-67-3 1β-benzoyl-5,9-dimethyl-7-hexanal-6-one 
• 102058-70-8 2,4-dimethyl-3(1-benzoyl-1-acetyl-butan-4-yl)-1-acetoxy benzene 
• 107449-62-7 Benzoic acid 1',4'a-dimethyl-3',4',4'a,5',6',7'-hexahydro-1'H-spiro[[1,3]dioxolane-2,2'-naphthalen]-5'-yl ester 
• 107449-61-6 Benzoic acid (4'aS,5'S)-1',4'a-dimethyl-4',4'a,5',6',7',8'-hexahydro-3'H-spiro[[1,3]dioxolane-2,2'-naphthalen]-5'-yl ester 

Relevant academic research and scientific papers

SYNTHESIS OF (+/-)-1β-METHOXY-9β,7β-EPOXY-5α-METHYL-TRANS-DECALIN

The ketal-ketone (14), prepared from dione (3), was converted to the olefin (16) which on reduction and methylation yielded the ketone (18).The alcohol (19), obtained by reduction with sodium and n-propanol, on oxidation with lead tetraacetate in benzene

ACID CATALYSED NOVEL REARRANGEMENT OF BICYCLIC DIENONE

The dienone (4) on heating with methanolic hydrochloric acid underwent ring cleavage yielding the aromatic ketal (6) which on acid hydrolysis produced the aldehyde (7).Similar treatment of the dienone (4) with acetic anhydride and p-toluenesulfonic acid f