1020673-70-4

Upstream product

• 6999-03-7 1-bromo-4-(trimethylsilyl)benzene 
• 1679-18-1 4-Chlorophenylboronic acid 
• 73183-34-3 bis(pinacol)diborane 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 17865-11-1 (4-(trimethylsilyl)phenyl)boronic acid 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 711603-51-9 (4'-(trimethylsilyl)-[1,1'-biphenyl]-4-yl)boronic acid 
• 92-86-4 4-(4-bromophenyl)bromobenzene 
• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 17908-91-7 (4′-bromobiphenyl-4-yl)(trimethyl)silane 

Relevant academic research and scientific papers

Influence of the structure of electron-donating aromatic units in organosilicon luminophores based on 2,1,3-benzothiadiazole electron-withdrawing core on their absorption-luminescent properties

A series of new linear π-conjugated oligomers consisting of five conjugated rings based on 2,1,3-benzothiadiazole (BTD) electron-withdrawing group and various combinations of 2,5-thiophene and 1,4-phenylene electron-donating units with terminal trimethyls

Anthracene, Triphenylene derivatives and organic electroluminescent device including the same

It provides an anthrasene or tripenylene derivatives that contribute to substantial light efficiency and viewing angle improvement of organic field-of-view light emitting elements. Organic field light emitting device according to the present invention, the first electrode; Second electrode; One or more organic layers disposed between the first electrode and the second electrode; And comprises a capping layer, the organic material layer or capping layer comprises an anthracene or tripenylene derivative represented by the following formula (1). [Formula 1] (In formula (in Formula 1, each subducer is as defined in the detailed description of the invention.)

Photoinduced Deaminative Borylation of Unreactive Aromatic Amines Enhanced by CO2

Herein, direct unreactive C-N borylation of aromatic amines by a photocatalyst was achieved. The C-N borylation of aromatic amines with bis(pinacolato)diboron (B2pin2) proceeded using a pyrene catalyst under light irradiation to afford desired borylated products and aminoborane as a byproduct. The yield of the borylated product improved under a CO2 atmosphere which probably reduced the inhibitory effect of aminoborane. Mechanistic studies suggested that the C-N bond cleavage and C-B bond formation proceeded via a concerted pathway.

Light-Induced Gold-Catalyzed Hiyama Arylation: A Coupling Access to Biarylboronates

Organoboron compounds are versatile synthetic building blocks. We herein report a new strategy, a photochemical gold-catalyzed chemo-selective Hiyama arylation of B,Si bifunctionalized reagents with diazonium salts, which is orthogonal to common strategies and therefore a unique tool for synthesis of valuable biarylboronates. With this new methodology a wide array of diversely functionalized sp2- and sp3-hybridized biarylboronates were obtained. Notably, the synergism of gold catalysis with copper catalysis or palladium catalysis, allows for one-pot iterative C?X (heteroatom) and C?C couplings for the rapid assembly of several simple fragments to relatively complex molecules. Mechanistic studies indicated that photosensitizer-free conditions were superior to gold/Ru(bpy)3Cl2 dual catalysis.